Double Stabilization of Highly Strained Six-Membered Rings by Phosphonium and Transition Metal

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	Double Stabilization of Highly Strained Six-Membered Rings by Phosphonium and Transition Metal
	Zhu Congqing ; Cao Xiaoyu ; Xia Haiping ; Cao XY(曹晓宇) ; Xia HP(夏海平)
刊名	http://dx.doi.org/10.6023/cjoc201301084
	2013
关键词	INDEPENDENT CHEMICAL-SHIFTS COMPLEX AROMATICITY METALLABENZYNES OSMABENZYNE ARYNES CHEMISTRY REACTIVITY CARBYNE OSMIUM
英文摘要	National Basic Research Program of China [2012CB821600]; National Natural Science Foundation of China [21174115, 20925208]; Program for Changjiang Scholars and Innovative Research Team in University; Cycloalkynes and cyclocumulenes have attracted considerable attention because they are key intermediates in organic synthesis. Stabilization of these highly active species remains a challenge for synthetic chemists. Recently, we found that phosphonium and transition metal replacement can double stabilize these species. Using this strategy, a series of highly strained six-membered rings with remarkable stability have been synthesized. Herein, the latest progress of our group is reviewed.
语种	英语
出版者	SCIENCE PRESS
内容类型	期刊论文
源URL	[http://dspace.xmu.edu.cn/handle/2288/89075]
专题	化学化工－已发表论文
推荐引用方式 GB/T 7714	Zhu Congqing,Cao Xiaoyu,Xia Haiping,et al. Double Stabilization of Highly Strained Six-Membered Rings by Phosphonium and Transition Metal[J]. http://dx.doi.org/10.6023/cjoc201301084,2013.
APA	Zhu Congqing,Cao Xiaoyu,Xia Haiping,曹晓宇,&夏海平.(2013).Double Stabilization of Highly Strained Six-Membered Rings by Phosphonium and Transition Metal.http://dx.doi.org/10.6023/cjoc201301084.
MLA	Zhu Congqing,et al."Double Stabilization of Highly Strained Six-Membered Rings by Phosphonium and Transition Metal".http://dx.doi.org/10.6023/cjoc201301084 (2013).