Formation and catalytic activity of novel water soluble di [ethylenediaminetetraacetato bis(N-oxido)] lanthanides

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	Formation and catalytic activity of novel water soluble di [ethylenediaminetetraacetato bis(N-oxido)] lanthanides
	Jiang, Xue ; Chen, Mao-Long ; Yang, Yu-Chen ; Zhou, Zhao-Hui ; Zhou CH(周朝晖)
刊名	http://dx.doi.org/10.1016/j.inoche.2013.05.012
	2013
关键词	MACROCYCLIC YTTERBIUM(III) COMPLEX 1ST EXAMPLE STRUCTURAL CHARACTERIZATIONS OXIDATION OXYGEN
英文摘要	National Science Foundation of China [21073150]; National Basic Research Program of China [2010CB732303]; Reaction of hydrogen peroxide with ethylenediaminetetraacetato lanthanides results in the formation of water-soluble isomorphous N-oxido ethylenediaminetetraacetato lanthanides K-5[Ln(edtaO(2))(2)] center dot 12H(2)O [Ln = La (1), Ce (2), Nd (3), H(4)edta = ethylenediaminetetraacetic acid C10H16O8N2] in weak basic solution, where lanthanide ions are octa-coordinated by two quardentate N-oxido edta ligands, resulting in a distorted anti-tetragonal prism. Based on the comparisons of solid and solution C-13 NMR spectra, these compounds are fully dissociated in solution. Catalytic reaction of K-5[La(edtaO(2))(2)]center dot 12H(2)O shows 96% conversion for the reaction of pyridine to pyridine N-oxide at 70 degrees C. (C) 2013 Elsevier B.V. All rights reserved.
语种	英语
出版者	ELSEVIER SCIENCE BV
内容类型	期刊论文
源URL	[http://dspace.xmu.edu.cn/handle/2288/88913]
专题	化学化工－已发表论文
推荐引用方式 GB/T 7714	Jiang, Xue,Chen, Mao-Long,Yang, Yu-Chen,et al. Formation and catalytic activity of novel water soluble di [ethylenediaminetetraacetato bis(N-oxido)] lanthanides[J]. http://dx.doi.org/10.1016/j.inoche.2013.05.012,2013.
APA	Jiang, Xue,Chen, Mao-Long,Yang, Yu-Chen,Zhou, Zhao-Hui,&周朝晖.(2013).Formation and catalytic activity of novel water soluble di [ethylenediaminetetraacetato bis(N-oxido)] lanthanides.http://dx.doi.org/10.1016/j.inoche.2013.05.012.
MLA	Jiang, Xue,et al."Formation and catalytic activity of novel water soluble di [ethylenediaminetetraacetato bis(N-oxido)] lanthanides".http://dx.doi.org/10.1016/j.inoche.2013.05.012 (2013).