New insight into the electronic shell of Au-38(SR)(24): a superatomic molecule

CORC > 厦门大学 > 化学化工－已发表论文

	New insight into the electronic shell of Au-38(SR)(24): a superatomic molecule
	Cheng, Longjiu ; Ren, Changda ; Zhang, Xiuzhen ; Yang, Jinlong ; Ren ZD(任长达)
刊名	http://dx.doi.org/10.1039/c2nr32888g
	2013
关键词	THIOLATE-PROTECTED AU-38 OPTICAL-ABSORPTION SPECTRA GOLD NANOCLUSTERS STRUCTURAL EVOLUTION CRYSTAL-STRUCTURE METAL-CLUSTERS NANOPARTICLES COMPLEXES AU-25 CORE
英文摘要	National Key Basic Research Program of China [2011CB921404]; National Natural Science Foundation of China [20903001, 21121003, 21273008, 21233007, 91021004]; CAS [XDB01020300]; 211 Project; outstanding youth foundation of Anhui University; Based on the recently proposed super valence bond model, in which superatoms can compose superatomic molecules by sharing valence pairs and nuclei for shell closure, the 23c-14e bi-icosahedral Au-23((+9)) core of Au-38(SR)(24) is proved to be a superatomic molecule. Molecular orbital analysis reveals that the Au-23((+9)) core is an exact analogue of the F-2 molecule in electronic configuration. Chemical bonding analysis by the adaptive natural density partitioning method confirms the superatomic molecule bonding framework of Au-38(24)(SR) in a straightforward manner.
语种	英语
出版者	ROYAL SOC CHEMISTRY
内容类型	期刊论文
源URL	[http://dspace.xmu.edu.cn/handle/2288/88876]
专题	化学化工－已发表论文
推荐引用方式 GB/T 7714	Cheng, Longjiu,Ren, Changda,Zhang, Xiuzhen,et al. New insight into the electronic shell of Au-38(SR)(24): a superatomic molecule[J]. http://dx.doi.org/10.1039/c2nr32888g,2013.
APA	Cheng, Longjiu,Ren, Changda,Zhang, Xiuzhen,Yang, Jinlong,&任长达.(2013).New insight into the electronic shell of Au-38(SR)(24): a superatomic molecule.http://dx.doi.org/10.1039/c2nr32888g.
MLA	Cheng, Longjiu,et al."New insight into the electronic shell of Au-38(SR)(24): a superatomic molecule".http://dx.doi.org/10.1039/c2nr32888g (2013).