The synthesis and enhancement of the surface properties of polyfluorene-based photoelectric materials by introducing fluoromonomers

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	The synthesis and enhancement of the surface properties of polyfluorene-based photoelectric materials by introducing fluoromonomers
	Wang, Jian-Jian ; Zhou, Yin-Ning ; Wang, Ping ; Luo, Zheng-Hong ; Luo ZH(罗正鸿)
刊名	http://dx.doi.org/10.1039/c3ra22682d
	2013
关键词	2-PERFLUOROOCTYLETHYL METHACRYLATE UNITS TRANSFER RADICAL POLYMERIZATION STABLE HYDROPHOBIC SURFACES PERFLUOROALKYL SIDE-CHAINS COIL DIBLOCK COPOLYMERS BLOCK-COPOLYMERS SET-LRP RAFT POLYMERIZATION ORGANIC-SOLVENTS ENERGY TRANSFER
英文摘要	National Ministry of Science and Technology of China [2012CB21500402]; National Natural Science Foundation of China [21076171, 21276213]; A series of fluorene-based rod-coil block copolymers with different lengths of fluorine-containing coil segments (poly[2,7-(9,9-dihexylfluorene)]-block-poly (2,2,3,3,4,4,4-heptafluorobutyl methacrylate), PF-b-PHFBMA) were well designed and successfully synthesized via atom transfer radical polymerization (ATRP). The thermal behavior, optical properties and surface properties of these rod-coil block copolymers were investigated. The thermal properties of the copolymers presented a good thermal stability, while the optical properties did not show a noticeable dependence on the lengths of the coil segments. In addition, they showed a high dependence on the self-assembly behavior in selective solvents. The surface properties were obviously influenced by the structure of the micelles formed in different selective solvents (i.e. THF, CHCl3 and C2F3Cl3). The incorporation of the fluorine-containing coil segments in the polyfluorene-based polymers yielded a low energy surface and various interesting surface morphologies, which gives the polymers many potential applications.
语种	英语
出版者	ROYAL SOC CHEMISTRY
内容类型	期刊论文
源URL	[http://dspace.xmu.edu.cn/handle/2288/88815]
专题	化学化工－已发表论文
推荐引用方式 GB/T 7714	Wang, Jian-Jian,Zhou, Yin-Ning,Wang, Ping,et al. The synthesis and enhancement of the surface properties of polyfluorene-based photoelectric materials by introducing fluoromonomers[J]. http://dx.doi.org/10.1039/c3ra22682d,2013.
APA	Wang, Jian-Jian,Zhou, Yin-Ning,Wang, Ping,Luo, Zheng-Hong,&罗正鸿.(2013).The synthesis and enhancement of the surface properties of polyfluorene-based photoelectric materials by introducing fluoromonomers.http://dx.doi.org/10.1039/c3ra22682d.
MLA	Wang, Jian-Jian,et al."The synthesis and enhancement of the surface properties of polyfluorene-based photoelectric materials by introducing fluoromonomers".http://dx.doi.org/10.1039/c3ra22682d (2013).