Two polymeric 36-metal pure lanthanide nanosize clusters

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	Two polymeric 36-metal pure lanthanide nanosize clusters
	Wu, Mingyan ; Jiang, Feilong ; Kong, Xiangjian ; Yuan, Daqiang ; Long, Lasheng ; Al-Thabaiti, Shaeel A. ; Hong, Maochun ; Kong XJ(孔祥建) ; Long LS(龙腊生)
刊名	http://dx.doi.org/10.1039/c3sc50887k
	2013
关键词	ENHANCED MAGNETIC COOLERS SINGLE-MOLECULE MAGNET COORDINATION CHEMISTRY RELAXATION BEHAVIOR METAL-IONS COMPLEXES POLYNUCLEAR FRAMEWORK LN REFRIGERANTS
英文摘要	973 Program [2011CBA00507, 2011CB932504]; National Natural Science Foundation of China [21131006]; Natural Science Foundation of Fujian Province; Two rarely seen 2D coordination polymers based on huge 36-metal pure lanthanide clusters, {[Gd-36(NA)(36)(OH)(49)(O)(6)(NO3)(6)(N-3)(3)(H2O)(20)]Cl-2 center dot 28H(2)O}(n) (1) and {[Dy-36(NA)(36)(OH)(49)(O)(6)(NO3)(6)(N-3)(3-)(H2O)(20)]Cl-2 center dot 28H(2)O}(n) (2) (HNA = nicotinic acid), were synthesized and structurally characterized. The spherical Ln(36) skeleton can be viewed as the aggregation of one cyclohexane chair-like Ln(24) wheel and two identical tripod-like Ln(6) units. The coordination of the carboxylic groups of the NA ligands with the Ln(III) cations results in a square layer. Additionally, compound 1 possesses a large MCE of 39.66 J kg(-1) K-1 and compound 2 exhibits slow relaxation of the magnetization.
语种	英语
出版者	ROYAL SOC CHEMISTRY
内容类型	期刊论文
源URL	[http://dspace.xmu.edu.cn/handle/2288/88758]
专题	化学化工－已发表论文
推荐引用方式 GB/T 7714	Wu, Mingyan,Jiang, Feilong,Kong, Xiangjian,et al. Two polymeric 36-metal pure lanthanide nanosize clusters[J]. http://dx.doi.org/10.1039/c3sc50887k,2013.
APA	Wu, Mingyan.,Jiang, Feilong.,Kong, Xiangjian.,Yuan, Daqiang.,Long, Lasheng.,...&龙腊生.(2013).Two polymeric 36-metal pure lanthanide nanosize clusters.http://dx.doi.org/10.1039/c3sc50887k.
MLA	Wu, Mingyan,et al."Two polymeric 36-metal pure lanthanide nanosize clusters".http://dx.doi.org/10.1039/c3sc50887k (2013).