Further Understanding on the Measurement Methods for Solid-State Circular Dichroism Spectroscopy-Discussion on Concentration Effects

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	Further Understanding on the Measurement Methods for Solid-State Circular Dichroism Spectroscopy-Discussion on Concentration Effects
	Zhang Hui ; Yan Jian-Xin ; Wu Shu-Ting ; Li Dan ; Wan Shi-Gang ; Ding Lei ; Lin Li-Rong ; Zhang H(章慧) ; Lin LR(林丽榕)
刊名	http://dx.doi.org/10.3866/PKU.WHXB201310152
	2013
关键词	ABSOLUTE-CONFIGURATION CORRELATIONS MIRROR SYMMETRY-BREAKING CHIRAL CRYSTAL-STRUCTURE SCHIFF-BASE COMPLEXES CD SPECTRA SPONTANEOUS RESOLUTION OPTICAL-ACTIVITY STEREOCHEMISTRY TRANSITION NETWORKS
英文摘要	National Natural Science Foundation of China [21273175, 21271150, 21001026]; State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences [20110006, 20130008]; In this paper, the recent developments in measurement methods of solid-state circular dichroism (CD) spectroscopy were summarized and discussed, especially the effects of concentration on solid-state CD spectral distortions. By reinspection and introspection of the solid-state CD spectra of four reported compounds, concentration gradient measurements were proved to be necessary for appropriate concentrations, which are greatly related to the chiroptical properties. The thin film solid-state CD measurements of the inherently chiral atropisomer (S)-1,1'-bi-2-naphthol (S-BINOL) were carried out with concentration gradient measurements. Using this film-state technique for the first time, the results show some subtle correlations between the CD curves and the special concentrations.
语种	英语
出版者	PEKING UNIV PRESS
内容类型	期刊论文
源URL	[http://dspace.xmu.edu.cn/handle/2288/88707]
专题	化学化工－已发表论文
推荐引用方式 GB/T 7714	Zhang Hui,Yan Jian-Xin,Wu Shu-Ting,et al. Further Understanding on the Measurement Methods for Solid-State Circular Dichroism Spectroscopy-Discussion on Concentration Effects[J]. http://dx.doi.org/10.3866/PKU.WHXB201310152,2013.
APA	Zhang Hui.,Yan Jian-Xin.,Wu Shu-Ting.,Li Dan.,Wan Shi-Gang.,...&林丽榕.(2013).Further Understanding on the Measurement Methods for Solid-State Circular Dichroism Spectroscopy-Discussion on Concentration Effects.http://dx.doi.org/10.3866/PKU.WHXB201310152.
MLA	Zhang Hui,et al."Further Understanding on the Measurement Methods for Solid-State Circular Dichroism Spectroscopy-Discussion on Concentration Effects".http://dx.doi.org/10.3866/PKU.WHXB201310152 (2013).