Two additive-induced isomeric aluminoborates templated by methylamine

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	Two additive-induced isomeric aluminoborates templated by methylamine
	Cao, Gao-Juan ; Lin, Jian ; Wang, Jin-Yun ; Zheng, Shou-Tian ; Fang, Wei-Hui ; Yang, Guo-Yu ; Lin J(林建)
刊名	http://dx.doi.org/10.1039/c0dt00303d
	2010
关键词	NONLINEAR-OPTICAL PROPERTIES OPEN-FRAMEWORK CRYSTAL-STRUCTURE HELICAL CHANNELS 1ST EXAMPLES BOROGERMANATE BORATE BOROPHOSPHATE TOPOLOGY ZEOLITE
英文摘要	NNSF of China [50872133, 20821061]; NNSF for Distinguished Young Scholars of China [20725101]; NSF of Fujian Province [E0510030]; 973 Program [2006CB932904]; FJIRSM [SZD07001]; Two additive-induced isomeric aluminoborates, (CH(3)NH(3))(2)(H(2)O)(2)[Al(B(5)O(10))] (1) and (CH(3)NH(3))(H(2)O)[Al(B(5)O(10))] (2), have been obtained by using small methylamine molecules as structure directing agents (SDA) under solvothermal conditions and characterized by elemental analysis, IR, TGA, powder X-ray diffraction, single-crystal X-ray diffraction, NLO determination, UV-vis spectral investigation, electronic structure calculation and ion exchange. Different arrangements of B(5)O(10) units and AlO(4) tetrahedra results in two different structures with two pairs of helical channels along [100] and [010] directions, respectively. Interestingly, the two frameworks with noncentrosymmetric and chiral space groups separately exhibit the same diamond topologies and display good second harmonic generation efficiencies of about 2.0 times the value of KDP.
语种	英语
出版者	DALTON T
内容类型	期刊论文
源URL	[http://dspace.xmu.edu.cn/handle/2288/88419]
专题	化学化工－已发表论文
推荐引用方式 GB/T 7714	Cao, Gao-Juan,Lin, Jian,Wang, Jin-Yun,et al. Two additive-induced isomeric aluminoborates templated by methylamine[J]. http://dx.doi.org/10.1039/c0dt00303d,2010.
APA	Cao, Gao-Juan.,Lin, Jian.,Wang, Jin-Yun.,Zheng, Shou-Tian.,Fang, Wei-Hui.,...&林建.(2010).Two additive-induced isomeric aluminoborates templated by methylamine.http://dx.doi.org/10.1039/c0dt00303d.
MLA	Cao, Gao-Juan,et al."Two additive-induced isomeric aluminoborates templated by methylamine".http://dx.doi.org/10.1039/c0dt00303d (2010).