Assembly of an undeca-nuclear nickel substituted POM through polycarboxylate ligand

CORC > 厦门大学 > 化学化工－已发表论文

	Assembly of an undeca-nuclear nickel substituted POM through polycarboxylate ligand
	Zheng, Yun-Yun ; Wen, Ru ; Kong, Xiang-Jian ; Long, La-Sheng ; Huang, Rong-Bin ; Zheng, Lan-Sun ; Long LS(龙腊生)
刊名	http://dx.doi.org/10.1039/c2dt12507b
	2012
关键词	TRANSITION-METAL CLUSTERS HYDROTHERMAL CONDITIONS CRYSTAL-STRUCTURES BUILDING-BLOCKS POLYOXOMETALATE COMBINATION MAGNETISM FRAMEWORK CHEMISTRY IONS
英文摘要	973 Project from MSTC [2012CB821704]; NNSFC [20825103, 90922031, 21021061]; An undeca-nuclear nickel substituted POM, namely [Ni-(H2O)(6)][Ni-11(PW9O34)(2)(IDA)(3)(en)(2)(Hen)(2)(OH)(6)]center dot(H2O)(7)center dot(H(2)en)(2) (1) (en = 1,2-ethylenediamine, H(2)IDA = iminodiacetic acid), was synthesized through hydrothermal reaction of Na-6-PW9O34, en, H(2)IDA and NiCl2 center dot 6H(2)O. Single-crystal structure reveals that 1 can be viewed as Ni6PW9 and Ni5PW9 units linked by a mu(3)-O bridge and two IDA(2-) ligands. Magnetic investigation indicates the presence of dominantly ferrimagnetic interactions within the Ni-11 core. Electrochemistry study shows that 1 displays a stable and reproducible voltammetric graph.
语种	英语
内容类型	期刊论文
源URL	[http://dspace.xmu.edu.cn/handle/2288/64719]
专题	化学化工－已发表论文
推荐引用方式 GB/T 7714	Zheng, Yun-Yun,Wen, Ru,Kong, Xiang-Jian,et al. Assembly of an undeca-nuclear nickel substituted POM through polycarboxylate ligand[J]. http://dx.doi.org/10.1039/c2dt12507b,2012.
APA	Zheng, Yun-Yun.,Wen, Ru.,Kong, Xiang-Jian.,Long, La-Sheng.,Huang, Rong-Bin.,...&龙腊生.(2012).Assembly of an undeca-nuclear nickel substituted POM through polycarboxylate ligand.http://dx.doi.org/10.1039/c2dt12507b.
MLA	Zheng, Yun-Yun,et al."Assembly of an undeca-nuclear nickel substituted POM through polycarboxylate ligand".http://dx.doi.org/10.1039/c2dt12507b (2012).