Tetraaquatetrakis{μ(3)-3,3＇-[(E,E)-ethane-1,2-diylbis(nitrilomethylidyne)] benzene-1,2-diolato}octazinc(II) N,N-dimethylformamide hexasolvate

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	Tetraaquatetrakis{μ(3)-3,3＇-[(E,E)-ethane-1,2-diylbis(nitrilomethylidyne)] benzene-1,2-diolato}octazinc(II) N,N-dimethylformamide hexasolvate
	Xu, Qin-Juan ; Lin, Li-Rong ; Sun, Di ; Huang, Rong-Bin ; Zheng, Lan-Sun ; 黄荣彬
刊名	http://dx.doi.org/10.1107/S1600536809046923
	2009-12
关键词	LIGHT-EMITTING-DIODES SCHIFF-BASE LIGANDS ZINC COMPLEX RECOGNITION CRYSTAL ZN(II)
英文摘要	National Basic Research Program of China [2007CB815301]; Science & Technology Innovation Project of Xiamen University [K70025]; The asymmetric unit of the title compound [Zn-8(C16H12N2O4)(4)(H2O)(4)]center dot 6C(3)H(7)NO, consists of eight Zn-II cations, four tetravalent anionic ligands, L4- (L4- = 3,3'(1E,1'E)-(ethane-1,2-diylbis(azan-1-yl-1-ylidene))bis(methan1-yl-1-ylidene)dibenzene-1,2-bis(olate), four coordinated water molecules and six N,N-dimethylformamide solvate molecules. The coordination complex comprises an octanuclear Zn-II unit with its Zn-II centers coordinated in two discrete distorted square-pyramidal geometries. Four Zn-II atoms each coordinate to two nitrogen atoms and two phenolate oxygen atoms from an individual L4- ligand and one coordinated water molecule. The other four Zn-II atoms each bind to five phenolate oxygen atoms from three different L4- ligands. In the crystal structure, the Zn-II complex unit, coordinated water molecules and dimethylformamide solvate molecules are linked via O-H center dot center dot center dot O and C-H center dot center dot center dot O hydrogen bonds. Molecules are connected by additional intermolecular O-H center dot center dot center dot O and C-H center dot center dot center dot O hydrogen bonds, forming an extensive three dimensional framework.
语种	英语
内容类型	期刊论文
源URL	[http://dspace.xmu.edu.cn/handle/2288/64626]
专题	化学化工－已发表论文
推荐引用方式 GB/T 7714	Xu, Qin-Juan,Lin, Li-Rong,Sun, Di,等. Tetraaquatetrakis{μ(3)-3,3＇-[(E,E)-ethane-1,2-diylbis(nitrilomethylidyne)] benzene-1,2-diolato}octazinc(II) N,N-dimethylformamide hexasolvate[J]. http://dx.doi.org/10.1107/S1600536809046923,2009.
APA	Xu, Qin-Juan,Lin, Li-Rong,Sun, Di,Huang, Rong-Bin,Zheng, Lan-Sun,&黄荣彬.(2009).Tetraaquatetrakis{μ(3)-3,3＇-[(E,E)-ethane-1,2-diylbis(nitrilomethylidyne)] benzene-1,2-diolato}octazinc(II) N,N-dimethylformamide hexasolvate.http://dx.doi.org/10.1107/S1600536809046923.
MLA	Xu, Qin-Juan,et al."Tetraaquatetrakis{μ(3)-3,3＇-[(E,E)-ethane-1,2-diylbis(nitrilomethylidyne)] benzene-1,2-diolato}octazinc(II) N,N-dimethylformamide hexasolvate".http://dx.doi.org/10.1107/S1600536809046923 (2009).