Tetraaquatetrakis{mu(3)-3,3 '- (E,E)-ethane-1,2-diylbis(nitrilomethylidyne) benzene-1,2-diolato}octa zinc(II) N,N-dimethylformamide hexasolvate | |
Xu, Q. J. ; Lin, L. R. ; Sun, D. ; Huang, R. B. ; Zheng, L. S. ; Huang RB(黄荣彬) | |
刊名 | http://dx.doi.org/10.1107/S1600536809046923
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2009-12 | |
关键词 | LIGHT-EMITTING-DIODES SCHIFF-BASE LIGANDS ZINC COMPLEX RECOGNITION CRYSTAL ZN(II) |
英文摘要 | National Basic Research Program of China [2007CB815301]; Science & Technology Innovation Project of Xiamen University [K70025]; The asymmetric unit of the title compound [Zn-8(C16H12N2O4)(4)(H2O)(4)]center dot 6C(3)H(7)NO, consists of eight Zn-II cations, four tetravalent anionic ligands, L4- (L4- = 3,3'(1E,1'E)-(ethane-1,2-diylbis(azan-1-yl-1-ylidene))bis(methan1-yl-1-ylidene)dibenzene-1,2-bis(olate), four coordinated water molecules and six N,N-dimethylformamide solvate molecules. The coordination complex comprises an octanuclear Zn-II unit with its Zn-II centers coordinated in two discrete distorted square-pyramidal geometries. Four Zn-II atoms each coordinate to two nitrogen atoms and two phenolate oxygen atoms from an individual L4- ligand and one coordinated water molecule. The other four Zn-II atoms each bind to five phenolate oxygen atoms from three different L4- ligands. In the crystal structure, the Zn-II complex unit, coordinated water molecules and dimethylformamide solvate molecules are linked via O-H center dot center dot center dot O and C-H center dot center dot center dot O hydrogen bonds. Molecules are connected by additional intermolecular O-H center dot center dot center dot O and C-H center dot center dot center dot O hydrogen bonds, forming an extensive three dimensional framework. |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://dspace.xmu.edu.cn/handle/2288/64548] ![]() |
专题 | 化学化工-已发表论文 |
推荐引用方式 GB/T 7714 | Xu, Q. J.,Lin, L. R.,Sun, D.,et al. Tetraaquatetrakis{mu(3)-3,3 '- (E,E)-ethane-1,2-diylbis(nitrilomethylidyne) benzene-1,2-diolato}octa zinc(II) N,N-dimethylformamide hexasolvate[J]. http://dx.doi.org/10.1107/S1600536809046923,2009. |
APA | Xu, Q. J.,Lin, L. R.,Sun, D.,Huang, R. B.,Zheng, L. S.,&黄荣彬.(2009).Tetraaquatetrakis{mu(3)-3,3 '- (E,E)-ethane-1,2-diylbis(nitrilomethylidyne) benzene-1,2-diolato}octa zinc(II) N,N-dimethylformamide hexasolvate.http://dx.doi.org/10.1107/S1600536809046923. |
MLA | Xu, Q. J.,et al."Tetraaquatetrakis{mu(3)-3,3 '- (E,E)-ethane-1,2-diylbis(nitrilomethylidyne) benzene-1,2-diolato}octa zinc(II) N,N-dimethylformamide hexasolvate".http://dx.doi.org/10.1107/S1600536809046923 (2009). |
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