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	SYNTHESIS, STRUCTURE AND CATALYTIC-HYDROGENATION OF DINUCLEAR PALLADIUM(II) COMPLEX PH(2)P(O-C6H4CO)PDCL (2)CENTER-DOT2CH(2)CL(2)
	Gao, J. X. ; Wang, J. Z. ; Hu, S. Z. ; Wan, H. L. ; Gao JX(高景星)
	1995-05
关键词	DIPALLADIUM COMPLEX O-(DIPHENYLPHOSPHINO)BENZALDEHYDE CRYSTAL STRUCTURE CATALYTIC HYDROGENATION
英文摘要	The interaction of Pd(CH3CN)(2)Cl-2 and 1 equivalent of o-(diphenylphosphino) benzaldehyde in refluxing dichloromethane gives dinuclear palladium(II) complex [Ph(2)P(o-C5H4CO)PdCl](2) . 2CH(2)Cl(2) by the intramolecular elimination of HCl. The complex has been characterized by analytical and spectroscopic methods as well as X-ray diffraction analysis. Crystal data: [Pd2Cl2(C19H14OP)(2)] . 2CH(2)Cl(2), triclinic, P (1) over bar, a = 0.9304(3) nm, b = 1.0390 (2) nm, c = 1.1062(3) nm; a = 102.78(2) , beta = 97.35(3), gamma = 95.25(2)degrees, V = 1.0264 nm(3), M = 1032.17, Z = 1, D-c = 1.670 g/cm(3), mu = 13.695 cm(-1), F(000) = 512, final R = 0.036 for 1945 significant reflections. The complex as a catalyst for homogeneous hydrogenation of olefin has been investigated. The results indicate that the title complex is an active catalyst for hydrogenation of acrylic acid.
语种	英语
内容类型	期刊论文
源URL	[http://dspace.xmu.edu.cn/handle/2288/64318]
专题	化学化工－已发表论文
推荐引用方式 GB/T 7714	Gao, J. X.,Wang, J. Z.,Hu, S. Z.,et al. SYNTHESIS, STRUCTURE AND CATALYTIC-HYDROGENATION OF DINUCLEAR PALLADIUM(II) COMPLEX PH(2)P(O-C6H4CO)PDCL (2)CENTER-DOT2CH(2)CL(2)[J],1995.
APA	Gao, J. X.,Wang, J. Z.,Hu, S. Z.,Wan, H. L.,&高景星.(1995).SYNTHESIS, STRUCTURE AND CATALYTIC-HYDROGENATION OF DINUCLEAR PALLADIUM(II) COMPLEX PH(2)P(O-C6H4CO)PDCL (2)CENTER-DOT2CH(2)CL(2)..
MLA	Gao, J. X.,et al."SYNTHESIS, STRUCTURE AND CATALYTIC-HYDROGENATION OF DINUCLEAR PALLADIUM(II) COMPLEX PH(2)P(O-C6H4CO)PDCL (2)CENTER-DOT2CH(2)CL(2)".(1995).

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