Template-assisted syntheses of two novel porous zirconium methylphosphonates
Wu, ZB; Liu, ZM; Tian, P; He, YL; Xu, L; Yang, Y; Zhang, YY; Bao, XH; Liu, XM; Liu, XC
刊名microporous and mesoporous materials
2005-06-06
卷号81期号:1-3页码:175-183
关键词porous zirconium methylphosphonate template-assisted synthesis dibutyl methylphosphonate
ISSN号1387-1811
通讯作者刘中民
产权排序1;1
英文摘要two porous zirconium methylphosphonates (designated as zmpmi and zmpme respectively) were synthesized by using dibutyl methylphosphonate (dbmp) as a template. two efficient post-synthetic treatments were developed to remove the incorporated template without destroying the hybrid structures. the materials were characterized by sem, epma, tg, dta, ftir, and nmr. specific surface area and porosity were evaluated by bet, alpha(s)-plots and dft methods based on n-2 adsorption-desorption isotherms. the specific surface areas of zmpmi and zmpme are determined to be 279 and 403 m(2) g(-1) and the maxima of pore size distributions are at 0.7 and 1.3 nm respectively. (c) 2005 elsevier inc. all rights reserved.
WOS标题词science & technology ; physical sciences ; technology
类目[WOS]chemistry, applied ; chemistry, physical ; nanoscience & nanotechnology ; materials science, multidisciplinary
研究领域[WOS]chemistry ; science & technology - other topics ; materials science
关键词[WOS]aluminum methylphosphonate ; unidimensional channels ; phosphonate materials ; mesoporous materials ; crystal-structures ; extraction ; framework
收录类别SCI
原文出处true
语种英语
WOS记录号WOS:000229665200021
公开日期2010-11-30
内容类型期刊论文
源URL[http://159.226.238.44/handle/321008/80947]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, Nat Gas Utilizat & Appl Catalysis Lab, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
推荐引用方式
GB/T 7714
Wu, ZB,Liu, ZM,Tian, P,et al. Template-assisted syntheses of two novel porous zirconium methylphosphonates[J]. microporous and mesoporous materials,2005,81(1-3):175-183.
APA Wu, ZB.,Liu, ZM.,Tian, P.,He, YL.,Xu, L.,...&Liu, XC.(2005).Template-assisted syntheses of two novel porous zirconium methylphosphonates.microporous and mesoporous materials,81(1-3),175-183.
MLA Wu, ZB,et al."Template-assisted syntheses of two novel porous zirconium methylphosphonates".microporous and mesoporous materials 81.1-3(2005):175-183.
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