Assembly of an undeca-nuclear nickel substituted POM through polycarboxylate ligand | |
Zheng, Yun-Yun ; Wen, Ru ; Kong, Xiang-Jian ; Long, La-Sheng ; Huang, Rong-Bin ; Zheng, Lan-Sun ; Zheng LS(郑兰荪) | |
刊名 | http://dx.doi.org/10.1039/c2dt12507b |
2012 | |
关键词 | TRANSITION-METAL CLUSTERS HYDROTHERMAL CONDITIONS CRYSTAL-STRUCTURES BUILDING-BLOCKS POLYOXOMETALATE COMBINATION MAGNETISM FRAMEWORK CHEMISTRY IONS |
英文摘要 | 973 Project from MSTC [2012CB821704]; NNSFC [20825103, 90922031, 21021061]; An undeca-nuclear nickel substituted POM, namely [Ni-(H2O)(6)][Ni-11(PW9O34)(2)(IDA)(3)(en)(2)(Hen)(2)(OH)(6)]center dot(H2O)(7)center dot(H(2)en)(2) (1) (en = 1,2-ethylenediamine, H(2)IDA = iminodiacetic acid), was synthesized through hydrothermal reaction of Na-6-PW9O34, en, H(2)IDA and NiCl2 center dot 6H(2)O. Single-crystal structure reveals that 1 can be viewed as Ni6PW9 and Ni5PW9 units linked by a mu(3)-O bridge and two IDA(2-) ligands. Magnetic investigation indicates the presence of dominantly ferrimagnetic interactions within the Ni-11 core. Electrochemistry study shows that 1 displays a stable and reproducible voltammetric graph. |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://dspace.xmu.edu.cn/handle/2288/63955] |
专题 | 化学化工-已发表论文 |
推荐引用方式 GB/T 7714 | Zheng, Yun-Yun,Wen, Ru,Kong, Xiang-Jian,et al. Assembly of an undeca-nuclear nickel substituted POM through polycarboxylate ligand[J]. http://dx.doi.org/10.1039/c2dt12507b,2012. |
APA | Zheng, Yun-Yun.,Wen, Ru.,Kong, Xiang-Jian.,Long, La-Sheng.,Huang, Rong-Bin.,...&郑兰荪.(2012).Assembly of an undeca-nuclear nickel substituted POM through polycarboxylate ligand.http://dx.doi.org/10.1039/c2dt12507b. |
MLA | Zheng, Yun-Yun,et al."Assembly of an undeca-nuclear nickel substituted POM through polycarboxylate ligand".http://dx.doi.org/10.1039/c2dt12507b (2012). |
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