Tridecaaquadinitratohexasodium(I) bis[(trans-cyclohexane-1,2-diyldinitrilotetraacetato)nickelate(II)] | |
Long, Y. X. ; Long, L. S. ; Huang, R. B. ; Zheng, L. S. ; Ng, S. W. ; Zheng LS(郑兰荪) | |
刊名 | http://dx.doi.org/10.1107/S1600536805009359 |
2005-04 | |
关键词 | BIMETALLIC COMPOUNDS MOLECULAR-STRUCTURE CRYSTAL |
英文摘要 | In the title compound, [Na-6(NO3)(2)(H2O)(13)][Ni(C14H18N2O8)](2), the edta-like tetraanionic unit uses two N and four O atoms to chelate to the Ni atom so that the [Ni(C14H18N2O8)](2-) portion of the structure has the Ni atom in a cis-N2O4Ni octahedral geometry. The [Na-6(NO3)(2)H2O)(13)](4+) portion exists as a chain consisting of edge-sharing NaO6 octahedra; there are four independent Na atoms in the asymmetric unit. The vertices are derived from the O atoms of water molecules, the O atom of the nitrate group as well as the O atoms of the [Ni(C14H18N2O8)](2-) unit. The layer structure is consolidated by hydrogen bonds into a three-dimensional network. Two of the Na atoms and three of the water O atoms lie on special positions of site symmetry 2. |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://dspace.xmu.edu.cn/handle/2288/63870] |
专题 | 化学化工-已发表论文 |
推荐引用方式 GB/T 7714 | Long, Y. X.,Long, L. S.,Huang, R. B.,et al. Tridecaaquadinitratohexasodium(I) bis[(trans-cyclohexane-1,2-diyldinitrilotetraacetato)nickelate(II)][J]. http://dx.doi.org/10.1107/S1600536805009359,2005. |
APA | Long, Y. X.,Long, L. S.,Huang, R. B.,Zheng, L. S.,Ng, S. W.,&郑兰荪.(2005).Tridecaaquadinitratohexasodium(I) bis[(trans-cyclohexane-1,2-diyldinitrilotetraacetato)nickelate(II)].http://dx.doi.org/10.1107/S1600536805009359. |
MLA | Long, Y. X.,et al."Tridecaaquadinitratohexasodium(I) bis[(trans-cyclohexane-1,2-diyldinitrilotetraacetato)nickelate(II)]".http://dx.doi.org/10.1107/S1600536805009359 (2005). |
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