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	Halogen Bonds in Two Silver(I) Mixed-ligand Supramolecular Frameworks: Synthesis, Structure and Photoluminescence
	Sun, Di ; Huang, Rong-Bin ; Zheng, Lan-Sun ; Zheng LS(郑兰荪)
	2011-10
关键词	COORDINATION POLYMER CRYSTAL-STRUCTURE AG(I) COMPLEXES X-RAY CHEMISTRY HYDROGEN ANION TETRACHLOROPHTHALATE FUNCTIONALITY COPPER(I)
英文摘要	National Natural Science Foundation of China [20721001]; MSTC [2007CB815301]; Independent Innovation Foundation of Shandong University, IIFSDU; Two silver(I) tetrachlorophthalates incorporating aminopyrimidyl ligands, namely [Ag(4)(apym)(4)(tcpta)(2)](n) (1) and [Ag(2)(dmapym)(tcpta)](n) (2), (apym = 2-aminopyrimidine, dmapym = 2-amino-4,6-dimethylpyrimidine, H(2)tcpta = tetrachlorophthalic acid), were synthesized and characterized by elemental analysis, IR spectroscopy and single-crystal X-ray diffraction. Both 1 and 2 form sheets which are assembled into 3D supramolecular frameworks via halogen bonds, hydrogen bonds and pi center dot center dot center dot pi interactions. Even adding two more methyl groups to the pyrimidyl ring does not change the dimensions of 1 and 2, but it influences the arrangement of the N- and O-donors in the solid state which in turn results in different types of halogen bonds. The photoluminescence properties of 1 and 2 were investigated in the solid state at room temperature.
语种	英语
内容类型	期刊论文
源URL	[http://dspace.xmu.edu.cn/handle/2288/63822]
专题	化学化工－已发表论文
推荐引用方式 GB/T 7714	Sun, Di,Huang, Rong-Bin,Zheng, Lan-Sun,et al. Halogen Bonds in Two Silver(I) Mixed-ligand Supramolecular Frameworks: Synthesis, Structure and Photoluminescence[J],2011.
APA	Sun, Di,Huang, Rong-Bin,Zheng, Lan-Sun,&郑兰荪.(2011).Halogen Bonds in Two Silver(I) Mixed-ligand Supramolecular Frameworks: Synthesis, Structure and Photoluminescence..
MLA	Sun, Di,et al."Halogen Bonds in Two Silver(I) Mixed-ligand Supramolecular Frameworks: Synthesis, Structure and Photoluminescence".(2011).

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