Investigation of Reaction Mechanism of Amino Acids and Phosphorus Trichloride by P-31 NMR and ESI-MS/MS

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	Investigation of Reaction Mechanism of Amino Acids and Phosphorus Trichloride by P-31 NMR and ESI-MS/MS
	Guo Yanchun ; Cao Shuxia ; Xie Yali ; Zong Xiangkun ; Zhao Yufen ; Zhao YF(赵玉芬)
刊名	http://dx.doi.org/10.1002/cjoc.201190219
	2011-06
关键词	IONIZATION MASS-SPECTROMETRY PEPTIDE LIBRARIES CYCLIC POLYPHOSPHATES L-VALINE OXYCHLORIDE DIPEPTIDES OLIGOMERIZATION TRIPHOSPHATE RACEMIZATION ACTIVATION
英文摘要	National Natural Science Foundation of China [20672104, 20732004]; The reaction of amino acids and phosphorus trichloride in THF was studied by P-31 NMR tracing and ESI-MS/MS. A series of hydridophoranes and cyclic dipeptides were obtained. The reaction presented interesting diversity and the reaction mechanism was proposed. The mechanism suggests that phosphorus plays an important role in the synthesis of amino acid hydridophorane and cyclic dipeptides. The results also show that P-31 NMR and ESI-MS/MS are useful tools for the investigation of reaction mechanism.
语种	英语
内容类型	期刊论文
源URL	[http://dspace.xmu.edu.cn/handle/2288/63566]
专题	化学化工－已发表论文
推荐引用方式 GB/T 7714	Guo Yanchun,Cao Shuxia,Xie Yali,et al. Investigation of Reaction Mechanism of Amino Acids and Phosphorus Trichloride by P-31 NMR and ESI-MS/MS[J]. http://dx.doi.org/10.1002/cjoc.201190219,2011.
APA	Guo Yanchun,Cao Shuxia,Xie Yali,Zong Xiangkun,Zhao Yufen,&赵玉芬.(2011).Investigation of Reaction Mechanism of Amino Acids and Phosphorus Trichloride by P-31 NMR and ESI-MS/MS.http://dx.doi.org/10.1002/cjoc.201190219.
MLA	Guo Yanchun,et al."Investigation of Reaction Mechanism of Amino Acids and Phosphorus Trichloride by P-31 NMR and ESI-MS/MS".http://dx.doi.org/10.1002/cjoc.201190219 (2011).