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	Synthesis and Structural Characterization of Organic-Inorganic Hybrid Material (C(2)N(2)H(10)) [Zn(2)(Pol)(2)]with Zeolite DFT Topology
	Mao Shao-Yu ; Xie Yu ; Xie Zhao-Xiong ; Xie ZX(谢兆雄)
	2009-01-10
关键词	ZINC-PHOSPHATES FRAMEWORK
英文摘要	Since the first microporous zinc phosphates with zeolite-like topologies were reported by Gier and Stucky, it has attracted much attention from chemists and materials scientists due to their chemical and physical properties and the applications as catalysts, nonlinear optical materials and ion exchangers, etc.. With a view to explore a new microporous materials, an open-framework organic-inorganic hybrid zinc phosphate was synthesized by hydrothermal method when ZnCl2 and H3PO4 were chosen as raw materials, DETA as template ;agent. Its structure was determined by single-crystal X-ray diffraction. Crystal data: tetragonal, space group P4(2)bc with lattice parameters a = b = 1.46850 (2) nm, c = 0.89274 (2) nm, alpha = beta = gamma = 90 degrees, V = 1.92519(6) nm(3), Z = 8, D-c =2. 641 g/cm(3). The title compound was also characterized by IR spectroscopy and TG-DTA. Luminescent measurement of (C2N2H10) [Zn-2(PO4)(2)] shows a emission band between 665 and 688 nm when excited with 451 nm UV light. The title compound may be found its applications in red lightemitting devices.
语种	英语
内容类型	期刊论文
源URL	[http://dspace.xmu.edu.cn/handle/2288/63308]
专题	化学化工－已发表论文
推荐引用方式 GB/T 7714	Mao Shao-Yu,Xie Yu,Xie Zhao-Xiong,et al. Synthesis and Structural Characterization of Organic-Inorganic Hybrid Material (C(2)N(2)H(10)) [Zn(2)(Pol)(2)]with Zeolite DFT Topology[J],2009.
APA	Mao Shao-Yu,Xie Yu,Xie Zhao-Xiong,&谢兆雄.(2009).Synthesis and Structural Characterization of Organic-Inorganic Hybrid Material (C(2)N(2)H(10)) [Zn(2)(Pol)(2)]with Zeolite DFT Topology..
MLA	Mao Shao-Yu,et al."Synthesis and Structural Characterization of Organic-Inorganic Hybrid Material (C(2)N(2)H(10)) [Zn(2)(Pol)(2)]with Zeolite DFT Topology".(2009).

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