Synthesis and Characterization of beta-Diketiminate Germanium(II) Compounds | |
Yang, Ying ; Zhao, Na ; Wu, Yile ; Zhu, Hongping ; Roesky, Herbert W. ; Zhu HP(朱红平) | |
刊名 | http://dx.doi.org/10.1021/ic202388d
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2012-02-20 | |
关键词 | TRANSITION-METAL COMPLEXES N-H BOND DIVALENT GERMANIUM CARBENE ANALOGS STRUCTURAL-CHARACTERIZATION MONOMERIC GERMANIUM(II) GERMYLENE COMPLEXES CRYSTAL-STRUCTURES REACTIVITY DERIVATIVES |
英文摘要 | NSFC [20902112, 20972129, 20423002]; China Postdoctoral Science Foundation [20090460748]; Deutsche Forschungsgemeinschaft; Reactions of LGeCl (L = CH[C(Me)N(Ar)](2); Ar = 2,6-iPr(2)C(6)H(3)) with KOtBu or LiR (R = 2-thienyl, N(H)Ar, PPh2) yielded the germanium(II) compounds LGeR [R = OtBu (1), 2-thienyl (2), N(H)Ar (3), PPh2 (4)]. The reduction of (2-thienyl)(2)PCl with lithium afforded the diphosphane [(2-thienyl)(2)P](2) (5). The treatment of (2-thienyl)(2)PCl with LiAlH4 or KHBtBu(3) led to the formation of (2-thienyl)(2)PH (6). The NHC-assisted reaction of LGeCl and 6 resulted in the isolation of LGeP(2-thienyl)(2) (7). This is the first example where NHC is used for eliminating HCl from compounds with P-H and Ge-Cl bonds. All solid products were characterized by elemental analysis, NMR and IR spectroscopy, and single-crystal X-ray structure determination. |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://dspace.xmu.edu.cn/handle/2288/62170] ![]() |
专题 | 化学化工-已发表论文 |
推荐引用方式 GB/T 7714 | Yang, Ying,Zhao, Na,Wu, Yile,et al. Synthesis and Characterization of beta-Diketiminate Germanium(II) Compounds[J]. http://dx.doi.org/10.1021/ic202388d,2012. |
APA | Yang, Ying,Zhao, Na,Wu, Yile,Zhu, Hongping,Roesky, Herbert W.,&朱红平.(2012).Synthesis and Characterization of beta-Diketiminate Germanium(II) Compounds.http://dx.doi.org/10.1021/ic202388d. |
MLA | Yang, Ying,et al."Synthesis and Characterization of beta-Diketiminate Germanium(II) Compounds".http://dx.doi.org/10.1021/ic202388d (2012). |
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