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	Stereoselective construction of an unprecedented 7-8 fused ring system in micrandilactone a by [3,3]-sigmatropic rearrangement
	Zhang, Yan-Dong ; Ren, Wei-Wu ; Lan, Yu ; Xiao, Qing ; Wang, Kai ; Xu, Jie ; Chen, Jia-Hua ; Yang, Zhen ; Zhang YD(张延东)
	2008
关键词	PAUSON-KHAND REACTION CLAISEN REARRANGEMENT ENYNE METATHESIS 8-MEMBERED RINGS STEREOCONTROLLED SYNTHESIS ASYMMETRIC INDUCTION 5+2+1 CYCLOADDITION THERMAL REACTIONS NATURAL-PRODUCTS STEREOCHEMISTRY
英文摘要	The 7-8 bicyclic ring system of micrandilactone A (1) with the required stereochemistry and functional groups was constructed by a Bu3Al-promoted Claisen rearrangement. Computational studies indicated that the exocyclic vinyl ether undergoes a [3,3] sigmatropic process via a chairlike transition state to afford exclusively the Z-double bond in the newly generated 8-membered ring with a high level of chirality transfer.
语种	英语
内容类型	期刊论文
源URL	[http://dspace.xmu.edu.cn/handle/2288/61971]
专题	化学化工－已发表论文
推荐引用方式 GB/T 7714	Zhang, Yan-Dong,Ren, Wei-Wu,Lan, Yu,et al. Stereoselective construction of an unprecedented 7-8 fused ring system in micrandilactone a by [3,3]-sigmatropic rearrangement[J],2008.
APA	Zhang, Yan-Dong.,Ren, Wei-Wu.,Lan, Yu.,Xiao, Qing.,Wang, Kai.,...&张延东.(2008).Stereoselective construction of an unprecedented 7-8 fused ring system in micrandilactone a by [3,3]-sigmatropic rearrangement..
MLA	Zhang, Yan-Dong,et al."Stereoselective construction of an unprecedented 7-8 fused ring system in micrandilactone a by [3,3]-sigmatropic rearrangement".(2008).

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