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	Antarafacial Mediation of Oxygen Delivery by a Phenylsulfinyl Group in the Epoxidation of Proximal Double Bonds: Intramolecular Trapping of an Early Pummerer Intermediate with Stereoelectronic Control
	Zhang, Yandong ; Lee, Jun Hee ; Danishefsky, Samuel J. ; Zhang YD(张延东)
	2011
关键词	SULFONIUM SALTS DERIVATIVES
英文摘要	Stereospecific intramolecular antarafacial epoxidation of a double bond via an early Pummerer reaction intermediate has been demonstrated. The intermediate is presumably generated via trifluoroacetylation of a sulfoxide precursor. Ionization of trifluoroacetate would formally generate a dipositive "sulfenium" equivalent. This species attacks an otherwise unactivated, proximal olefinic linkage in an antiperiplanar fashion, with trifluoroacetate serving as the nucleophile. Proposed mechanistic intermediates were characterized structurally (in several cases by crystallographic means) and shown to serve as precursors en route to the final antarafacial epoxides. The sense of the cyclization seems to be driven by principles inherent in Markovnikov's rule.
语种	英语
内容类型	期刊论文
源URL	[http://dspace.xmu.edu.cn/handle/2288/61964]
专题	化学化工－已发表论文
推荐引用方式 GB/T 7714	Zhang, Yandong,Lee, Jun Hee,Danishefsky, Samuel J.,et al. Antarafacial Mediation of Oxygen Delivery by a Phenylsulfinyl Group in the Epoxidation of Proximal Double Bonds: Intramolecular Trapping of an Early Pummerer Intermediate with Stereoelectronic Control[J],2011.
APA	Zhang, Yandong,Lee, Jun Hee,Danishefsky, Samuel J.,&张延东.(2011).Antarafacial Mediation of Oxygen Delivery by a Phenylsulfinyl Group in the Epoxidation of Proximal Double Bonds: Intramolecular Trapping of an Early Pummerer Intermediate with Stereoelectronic Control..
MLA	Zhang, Yandong,et al."Antarafacial Mediation of Oxygen Delivery by a Phenylsulfinyl Group in the Epoxidation of Proximal Double Bonds: Intramolecular Trapping of an Early Pummerer Intermediate with Stereoelectronic Control".(2011).

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