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Tandem Michael addition/ylide epoxidation for the synthesis of highly functionalized cyclohexadiene epoxide derivatives
Wang, Qing-Gang ; Deng, Xian-Ming ; Zhu, Ben-Hu ; Ye, Long-Wu ; Sun, Xiu-Li ; Li, Chuan-Ying ; Zhu, Chun-Yin ; Shen, Qi ; Tang, Yong ; Ye LW(叶龙武)
2008
关键词ALKENYL AMINOSULFOXONIUM SALTS ENANTIOSELECTIVE SYNTHESIS ASYMMETRIC-SYNTHESIS SULFONIUM YLIDES DIASTEREOSELECTIVE SYNTHESIS CYCLOPROPANATION REACTIONS STEREOSELECTIVE-SYNTHESIS MIGRATORY CYCLIZATION DOMINO REACTIONS GLYCIDIC AMIDES
英文摘要A highly efficient diastereoselective synthesis of cyclohexadiene epoxide derivatives with a multi-stereocenter has been developed via a tandem ylide Michael addition/epoxidation. By employing a chiral sulfonium ylide, up to 96% ee can be achieved in good yields.
语种英语
内容类型期刊论文
源URL[http://dspace.xmu.edu.cn/handle/2288/61390]  
专题化学化工-已发表论文
推荐引用方式
GB/T 7714
Wang, Qing-Gang,Deng, Xian-Ming,Zhu, Ben-Hu,et al. Tandem Michael addition/ylide epoxidation for the synthesis of highly functionalized cyclohexadiene epoxide derivatives[J],2008.
APA Wang, Qing-Gang.,Deng, Xian-Ming.,Zhu, Ben-Hu.,Ye, Long-Wu.,Sun, Xiu-Li.,...&叶龙武.(2008).Tandem Michael addition/ylide epoxidation for the synthesis of highly functionalized cyclohexadiene epoxide derivatives..
MLA Wang, Qing-Gang,et al."Tandem Michael addition/ylide epoxidation for the synthesis of highly functionalized cyclohexadiene epoxide derivatives".(2008).
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