Synthesis of an osmafuran from photochemical hydrolysis of OsCl2(CH=C(PPh3)C(O)-eta(2)-CH=CH2)(PPh3)(2) | |
He, X. M. ; Liu, Q. X. ; Gong, L. ; Lin, Y. M. ; Wen, T. B. ; He XM(何旭敏) | |
刊名 | http://dx.doi.org/10.1016/j.inoche.2009.12.016
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2010-03 | |
关键词 | BOND ACTIVATION H BOND COMPLEXES OSMIUM |
英文摘要 | National Science Foundation of China [20772100]; program for New Century Excellent Talents in University of China [NCET-08-0471]; Program for New Century Excellent Talents in Fujian Province University; Young Talent Project of the Department of Science an; The eta(2)-alkene coordinated alpha,beta-unsaturated ketone complex Os(CH=C(PPh3)C(O)-eta(2)-CH=CH2)Cl-2(PPh3)(2) (3) is very stable even at elevated temperature due to the strong steric hindrance effect of PPh3 ligands. However, compound 3 in a chloroform solution can be almost quantitatively converted into the corresponding osmafuran [OsCl(CO)(PPh3)(2)(CHC(PPh3)C(CH3)O)]Cl (6) via hydrolysis of the eta(2)-coordinated olefin under photochemical conditions Osmafuran 6 has been characterized by single crystal X-ray diffraction analysis, NMR spectroscopy and elemental analysis data The UV-induced reaction provides a new highly efficient method for preparation of osmafurans by hydrolysis of eta(2)-alpha,beta-unsaturated ketone complexes (C) 2009 Elsevier B.V. All rights reserved |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://dspace.xmu.edu.cn/handle/2288/61295] ![]() |
专题 | 化学化工-已发表论文 |
推荐引用方式 GB/T 7714 | He, X. M.,Liu, Q. X.,Gong, L.,et al. Synthesis of an osmafuran from photochemical hydrolysis of OsCl2(CH=C(PPh3)C(O)-eta(2)-CH=CH2)(PPh3)(2)[J]. http://dx.doi.org/10.1016/j.inoche.2009.12.016,2010. |
APA | He, X. M.,Liu, Q. X.,Gong, L.,Lin, Y. M.,Wen, T. B.,&何旭敏.(2010).Synthesis of an osmafuran from photochemical hydrolysis of OsCl2(CH=C(PPh3)C(O)-eta(2)-CH=CH2)(PPh3)(2).http://dx.doi.org/10.1016/j.inoche.2009.12.016. |
MLA | He, X. M.,et al."Synthesis of an osmafuran from photochemical hydrolysis of OsCl2(CH=C(PPh3)C(O)-eta(2)-CH=CH2)(PPh3)(2)".http://dx.doi.org/10.1016/j.inoche.2009.12.016 (2010). |
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