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	The investigation of electro-oxidation behavior and in-situ surface enhanced Raman spectrum of isosafrole on rough Pt
	Zhong, Q. L. ; Zhang, X. H. ; Su, X. Q. ; Zhang, L. ; Liu, Y. L. ; Ren, B. ; Tian, Z. Q. ; Ren B(任斌)
	2004
关键词	cyclic voltrammetry (CV) isosafrole (ISF) reaction mechanism electro-oxidation Raman spectrum
英文摘要	The oxidative behavior of isosafrole (ISF) in non-aqueous system on Pt was investigated by cyclic voltammery. When scanning from -0.55 to 1.95 V ( vs Ag/AgCl electrode) at a certain scan rate, two oxidation peaks and one reduction peak appeared. By scanning at different scan rate, the electro-oxidative behavior of isosafrole on Pt was confirmed to be controlled by concentration diffusion, as well as chemical reaction rate. By comparing the two isomers, ISF and SF safrole, the reactive mechanism was dcecussed. Moreover, the active oxidation group of ISF was identified to be the C = C from allyl by developing the in-situ surface enhanced Raman specrum.
语种	英语
内容类型	期刊论文
源URL	[http://dspace.xmu.edu.cn/handle/2288/61235]
专题	化学化工－已发表论文
推荐引用方式 GB/T 7714	Zhong, Q. L.,Zhang, X. H.,Su, X. Q.,et al. The investigation of electro-oxidation behavior and in-situ surface enhanced Raman spectrum of isosafrole on rough Pt[J],2004.
APA	Zhong, Q. L..,Zhang, X. H..,Su, X. Q..,Zhang, L..,Liu, Y. L..,...&任斌.(2004).The investigation of electro-oxidation behavior and in-situ surface enhanced Raman spectrum of isosafrole on rough Pt..
MLA	Zhong, Q. L.,et al."The investigation of electro-oxidation behavior and in-situ surface enhanced Raman spectrum of isosafrole on rough Pt".(2004).

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