Asymmetric transfer hydrogenation of ketones catalyzed by nickel complex with new PNO-type ligands | |
Dong, Zhen Rong ; Li, Yan Yun ; Yu, Shen Luan ; Sun, Guo Song ; Gao, Jing Xing ; Gao JX(高景星) | |
2012-05 | |
关键词 | Nickel complex NPO-type ligand Asymmetric transfer hydrogenation Ketones |
英文摘要 | The new polydentate mixed-N, P, O chiral ligands have been synthesized by the condensation of bis(o-formylphenyl)-phenylphosphane and R-phenylglycinol in CHCl3, and fully characterized by IR, NMR and EIMS spectra. These ligands were employed with a simple Ni complex Ni(PPhs)(2)Cl-2 in situ as catalytic systems for asymmetric transfer hydrogenation of ketones, and the corresponding optical alcohols were obtained with up to 84% ee under mild conditions. (C) 2012 Zhen Rong Dong. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.; National Natural Science Foundation of China [21173176]; Natural Science Foundation of Guangxi Province of China [0991016] |
语种 | 英语 |
出版者 | ELSEVIER SCIENCE INC |
内容类型 | 期刊论文 |
源URL | [http://dx.doi.org/10.1016/j.cclet.2012.02.005] ![]() |
专题 | 化学化工-已发表论文 |
推荐引用方式 GB/T 7714 | Dong, Zhen Rong,Li, Yan Yun,Yu, Shen Luan,et al. Asymmetric transfer hydrogenation of ketones catalyzed by nickel complex with new PNO-type ligands[J],2012. |
APA | Dong, Zhen Rong,Li, Yan Yun,Yu, Shen Luan,Sun, Guo Song,Gao, Jing Xing,&高景星.(2012).Asymmetric transfer hydrogenation of ketones catalyzed by nickel complex with new PNO-type ligands.. |
MLA | Dong, Zhen Rong,et al."Asymmetric transfer hydrogenation of ketones catalyzed by nickel complex with new PNO-type ligands".(2012). |
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