| Copper-Catalyzed Synthesis of Alkylphosphonates from H-Phosphonates and N-Tosylhydrazones | |
| Miao, Wenjun ; Gao, Yuzhen ; Li, Xueqin ; Gao, Yuxing ; Tang, Guo ; Tang G(唐果) ; Zhao, Yufen ; Zhao YF(赵玉芬) | |
| 2012-10 | |
| 关键词 | alkylphosphonates carbonyl compounds copper catalysis H-phosphonates N-tosylhydrazones |
| 英文摘要 | A new catalytic system for the alkylation of H-phosphonates and diphenylphosphine oxide with N-tosylhydrazones has been developed. In the presence of copper(I) iodide and base, H-phosphonates react with N-tosylhydrazones to afford the corresponding coupled alkylphosphonates in good to excellent yields without any ligands. Alkylphosphonates can also be prepared in a one-pot process directly from carbonyl compounds without the isolation of tosylhydrazone intermediates.; National Basic Research Program of China 2012CB821600 |
| 语种 | 英语 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 内容类型 | 期刊论文 |
| 源URL | [http://dx.doi.org/10.1002/adsc.201200295]  |
| 专题 | 化学化工－已发表论文 |
| 推荐引用方式 GB/T 7714 | Miao, Wenjun,Gao, Yuzhen,Li, Xueqin,et al. Copper-Catalyzed Synthesis of Alkylphosphonates from H-Phosphonates and N-Tosylhydrazones[J],2012. |
| APA | Miao, Wenjun.,Gao, Yuzhen.,Li, Xueqin.,Gao, Yuxing.,Tang, Guo.,...&赵玉芬.(2012).Copper-Catalyzed Synthesis of Alkylphosphonates from H-Phosphonates and N-Tosylhydrazones.. |
| MLA | Miao, Wenjun,et al."Copper-Catalyzed Synthesis of Alkylphosphonates from H-Phosphonates and N-Tosylhydrazones".(2012). |
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