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	SYNTHESIS, STRUCTURE AND CATALYTIC-HYDROGENATION OF DINUCLEAR PALLADIUM(II) COMPLEX [PH(2)P(O-C6H4CO)PDCL](2)CENTER-DOT2CH(2)CL(2)
	GAO, JX ; Gao JX(高景星) ; WANG, JZ ; Wang JZ(王金枝) ; HU, SZ ; Hu SZ(胡盛志) ; WAN, HL ; Wan HL(万惠霖)
	1995
关键词	DIPALLADIUM COMPLEX O-(DIPHENYLPHOSPHINO)BENZALDEHYDE CRYSTAL STRUCTURE CATALYTIC HYDROGENATION
英文摘要	The interaction of Pd(CH3CN)(2)Cl-2 and 1 equivalent of o-(diphenylphosphino) benzaldehyde in refluxing dichloromethane gives dinuclear palladium(II) complex [Ph(2)P(o-C5H4CO)PdCl](2) . 2CH(2)Cl(2) by the intramolecular elimination of HCl. The complex has been characterized by analytical and spectroscopic methods as well as X-ray diffraction analysis. Crystal data: [Pd2Cl2(C19H14OP)(2)] . 2CH(2)Cl(2), triclinic, P (1) over bar, a = 0.9304(3) nm, b = 1.0390 (2) nm, c = 1.1062(3) nm; a = 102.78(2) , beta = 97.35(3), gamma = 95.25(2)degrees, V = 1.0264 nm(3), M = 1032.17, Z = 1, D-c = 1.670 g/cm(3), mu = 13.695 cm(-1), F(000) = 512, final R = 0.036 for 1945 significant reflections. The complex as a catalyst for homogeneous hydrogenation of olefin has been investigated. The results indicate that the title complex is an active catalyst for hydrogenation of acrylic acid.
语种	中文
出版者	HIGHER EDUCATION PRESS
内容类型	期刊论文
源URL	[http://dspace.xmu.edu.cn/handle/2288/13721]
专题	化学化工－已发表论文
推荐引用方式 GB/T 7714	GAO, JX,Gao JX,WANG, JZ,et al. SYNTHESIS, STRUCTURE AND CATALYTIC-HYDROGENATION OF DINUCLEAR PALLADIUM(II) COMPLEX [PH(2)P(O-C6H4CO)PDCL](2)CENTER-DOT2CH(2)CL(2)[J],1995.
APA	GAO, JX.,高景星.,WANG, JZ.,王金枝.,HU, SZ.,...&万惠霖.(1995).SYNTHESIS, STRUCTURE AND CATALYTIC-HYDROGENATION OF DINUCLEAR PALLADIUM(II) COMPLEX [PH(2)P(O-C6H4CO)PDCL](2)CENTER-DOT2CH(2)CL(2)..
MLA	GAO, JX,et al."SYNTHESIS, STRUCTURE AND CATALYTIC-HYDROGENATION OF DINUCLEAR PALLADIUM(II) COMPLEX [PH(2)P(O-C6H4CO)PDCL](2)CENTER-DOT2CH(2)CL(2)".(1995).

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