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Kinetics of Irreversible Reaction on Platinum Single Crystal Electrodes
Yang, YY ; Yang YY(杨毅芸) ; Sun, SG ; Sun SG(孙世刚)
1997
关键词Platinum single crystal electrodes Formic acid Kinetics of irreversible reaction in situ FTIR spectroscopy
英文摘要The dissociative adsorption and oxidation of formic acid on Pt(100) single crystal electrode were investigated by using elect heniical techniques and in situ time resolved FTIR spectroscopy (TR-FTIRS), The results demonstrated that the distribution of the rate of dissociative adsorption of HCOOH on Pt(100) versus electrode potential yields a volcanic relationship between 0.25 d 0,25 V. Batted on results of TR-FTIRS, we concluded that the dissociative adsorption of HCOOH on Pt (100) can be a avoided by designing appropriate potential step program, winch is the basis of further studies, of the kinetics of direct oxidation of HCOOH into CO2 via reactive intermediates.
语种中文
出版者PEKING UNIV PRESS
内容类型期刊论文
源URL[http://dspace.xmu.edu.cn/handle/2288/13499]  
专题化学化工-已发表论文
推荐引用方式
GB/T 7714
Yang, YY,Yang YY,Sun, SG,et al. Kinetics of Irreversible Reaction on Platinum Single Crystal Electrodes[J],1997.
APA Yang, YY,杨毅芸,Sun, SG,&孙世刚.(1997).Kinetics of Irreversible Reaction on Platinum Single Crystal Electrodes..
MLA Yang, YY,et al."Kinetics of Irreversible Reaction on Platinum Single Crystal Electrodes".(1997).
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