Kinetics of Irreversible Reaction on Platinum Single Crystal Electrodes | |
Yang, YY ; Yang YY(杨毅芸) ; Sun, SG ; Sun SG(孙世刚) | |
1997 | |
关键词 | Platinum single crystal electrodes Formic acid Kinetics of irreversible reaction in situ FTIR spectroscopy |
英文摘要 | The dissociative adsorption and oxidation of formic acid on Pt(100) single crystal electrode were investigated by using elect heniical techniques and in situ time resolved FTIR spectroscopy (TR-FTIRS), The results demonstrated that the distribution of the rate of dissociative adsorption of HCOOH on Pt(100) versus electrode potential yields a volcanic relationship between 0.25 d 0,25 V. Batted on results of TR-FTIRS, we concluded that the dissociative adsorption of HCOOH on Pt (100) can be a avoided by designing appropriate potential step program, winch is the basis of further studies, of the kinetics of direct oxidation of HCOOH into CO2 via reactive intermediates. |
语种 | 中文 |
出版者 | PEKING UNIV PRESS |
内容类型 | 期刊论文 |
源URL | [http://dspace.xmu.edu.cn/handle/2288/13499] ![]() |
专题 | 化学化工-已发表论文 |
推荐引用方式 GB/T 7714 | Yang, YY,Yang YY,Sun, SG,et al. Kinetics of Irreversible Reaction on Platinum Single Crystal Electrodes[J],1997. |
APA | Yang, YY,杨毅芸,Sun, SG,&孙世刚.(1997).Kinetics of Irreversible Reaction on Platinum Single Crystal Electrodes.. |
MLA | Yang, YY,et al."Kinetics of Irreversible Reaction on Platinum Single Crystal Electrodes".(1997). |
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