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	Spectroelectrochemical studies of the conducting polymer of o-phenylenediamine
	Wu, LL ; Wu LL(吴玲玲) ; Luo, J ; Luo J(罗谨) ; Lin, ZH ; Lin ZH(林仲华)
	1997
关键词	spectroelectrochemistry poly-o-phenylenediamine redox mechanism
英文摘要	The redox mechanism of the conducting polymer film of poly-o-phenylenediamine (P-o-PD) in acid solution has been studied by cyclic voltammetry(CV), electrochemical insitu resonance Raman spectroscopy and UV-Vis subtractive reflectance spectroscopy, The results of the CV show that the redox process of P-o-PD is controlled by the surface processes and three steady redox states are formed in the redox process, The in-situ resonance Raman spectra not only verify the existence of the three steady states of P-o-PD, but also indicate that the structure of P-o-PD is dominated by a ladder polymer with phenazine rings, The three kinds of P-o-PD display different stabilities and UV-Vis aborption spectra, Furthermore, the in-situ time-resolved UV-Vis reflectance spectroscopy is used to study the dynamic redox process of P-o-PD, and a possible reaction mechanism is proposed at last.
语种	中文
出版者	HIGHER EDUCATION PRESS
内容类型	期刊论文
源URL	[http://dspace.xmu.edu.cn/handle/2288/13439]
专题	化学化工－已发表论文
推荐引用方式 GB/T 7714	Wu, LL,Wu LL,Luo, J,et al. Spectroelectrochemical studies of the conducting polymer of o-phenylenediamine[J],1997.
APA	Wu, LL,吴玲玲,Luo, J,罗谨,Lin, ZH,&林仲华.(1997).Spectroelectrochemical studies of the conducting polymer of o-phenylenediamine..
MLA	Wu, LL,et al."Spectroelectrochemical studies of the conducting polymer of o-phenylenediamine".(1997).

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