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	Dependence of surface enhanced Raman scattering of water on the hydrogen evolution reaction
	Chen, YX ; Tian, ZQ ; Tian ZQ(田中群)
	1998-05-27
英文摘要	Surface enhanced Raman scattering (SERS) of water with abnormal enhancement of the bending and libration modes can be detected at potentials where hydrogen evolution is occurring over Cu and Ag electrodes. The SERS intensity is critically dependent on the current density and hence related to the dissociation of water. The result infers that the interfacial water undergoing dissociation could possess a special structure involving a partially broken hydrogen bond and hence a corresponding intermediate electronic state. We suggest it is necessary to reconsider and modify existing SERS mechanism(s) to explain these results on reactive molecules undergoing surface reaction processes. (C) 1997 Elsevier Science B.V.
语种	英语
出版者	ELSEVIER SCIENCE BV
内容类型	期刊论文
源URL	[http://dx.doi.org/10.1016/S0009-2614(97)01255-4,]
专题	化学化工－已发表论文
推荐引用方式 GB/T 7714	Chen, YX,Tian, ZQ,Tian ZQ. Dependence of surface enhanced Raman scattering of water on the hydrogen evolution reaction[J],1998.
APA	Chen, YX,Tian, ZQ,&田中群.(1998).Dependence of surface enhanced Raman scattering of water on the hydrogen evolution reaction..
MLA	Chen, YX,et al."Dependence of surface enhanced Raman scattering of water on the hydrogen evolution reaction".(1998).

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