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	High-Nuclearity 3d-4f Clusters as Enhanced Magnetic Coolers and Molecular Magnets
	Jun-Bo Peng ; Peng JB(彭军波) ; Qian-Chong Zhang ; Zhang QC(张潜翀) ; Xiang-Jian Kong ; Kong XJ(孔祥建) ; Yan-Zhen Zheng(Xi An Jiao Tong Univ, Frontier Inst Sci & Technol, Ctr Appl Chem Res) ; Yan-Ping Ren ; Ren YP(任艳平) ; La-Sheng Long ; Long LS(龙腊生) ; Rong-Bin Huang ; Huang RB(黄荣彬) ; Lan-Sun Zheng ; Zheng LS(郑兰荪) ; Zhiping Zheng ; Zheng ZP(郑智平)
	2012-02-22
关键词	ATMOSPHERIC CARBON-DIOXIDE REFRIGERATION FIXATION RELAXATION COMPLEXES BEHAVIOR COPPER(II) FULLERENE IONS CAGE
英文摘要	通讯作者地址: Kong, XJ (通讯作者),Xiamen Univ, Dept Chem, Coll Chem & Chem Engn, State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Peoples R China 地址: 1. Xiamen Univ, Dept Chem, Coll Chem & Chem Engn, State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Peoples R China 2. Xi An Jiao Tong Univ, Frontier Inst Sci & Technol, Ctr Appl Chem Res, Xian 710054, Peoples R China 电子邮件地址: xjkong@xmu.edu.cn; lslong@xmu.edu.cn; Four 52-metal-ion 3d-4f cluster complexes featuring a common core of Ln(42)M(10) (Ln = Gd3+, Dy3+; M = Co2+/3+, Ni2+) were obtained through self-assembly of the metal ions templated by mixed anions (ClO4- and CO32-). Magnetic studies revealed that the Gd42Co10 and Gd42Ni10 clusters exhibit the largest magnetocaloric effect (MCE) among any known 3d-4f complexes. Replacement of Gd3+ ions with anisotropic Dy3+ ions caused significant changes in the magnetic behavior of the clusters; both DY42Co10 and Dy42Ni10 displayed slow relaxation of the magnetization.; NNSFC 20901064 20825103 21021061 90922031 Ministry of Science and Technology of China 2012CB821704 Fundamental Research Funds for the Central Universities 2010121016
语种	英语
出版者	AMER CHEMICAL SOC
内容类型	期刊论文
源URL	[http://dspace.xmu.edu.cn/handle/2288/13128]
专题	化学化工－已发表论文
推荐引用方式 GB/T 7714	Jun-Bo Peng,Peng JB,Qian-Chong Zhang,et al. High-Nuclearity 3d-4f Clusters as Enhanced Magnetic Coolers and Molecular Magnets[J],2012.
APA	Jun-Bo Peng.,彭军波.,Qian-Chong Zhang.,张潜翀.,Xiang-Jian Kong.,...&郑智平.(2012).High-Nuclearity 3d-4f Clusters as Enhanced Magnetic Coolers and Molecular Magnets..
MLA	Jun-Bo Peng,et al."High-Nuclearity 3d-4f Clusters as Enhanced Magnetic Coolers and Molecular Magnets".(2012).

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