A novel one-dimensional mixed ligands silver(I) coordination polymer containing two different chains | |
Fu-Jing Liu ; Liu FJ(刘福静) ; Di Sun ; Sun D(孙頔) ; Hong-Jun Hao ; Hao HJ(郝红君) ; Rong-Bin Huang ; Huang RB(黄荣彬) ; Lan-Sun Zheng ; Zheng LS(郑兰荪) | |
2012-04-25 | |
关键词 | Silver(I) 1,4-Bis(2-methylimidazol-1-ylmethyl)benzene Naphthalene-1,4-dicarboxylic acid Photoluminescence |
英文摘要 | 通讯作者地址: Sun, D (通讯作者),Shandong Univ, Sch Chem & Chem Engn, Jinan 250100, Shandong, Peoples R China 地址: 1. Shandong Univ, Sch Chem & Chem Engn, Jinan 250100, Shandong, Peoples R China 2. Xiamen Univ, Dept Chem, Coll Chem & Chem Engn, State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Fujian, Peoples R China 电子邮件地址: dsun@sdu.edu.cn; rbhuang@xmu.edu.cn; A mixed-ligand coordination polymer (CP) of the formula {[Ag-3(bmimb)(2) (ndca)(1.5)]center dot H2O}(n) (1) (where bmimb = 1,4-bis(2-methylimidazol-1-ylmethyl)benzene and H(2)ndca = naphthalene-1,4-dicarboxylic acid) was synthesized by reaction of Ag2O and bmimb ligand with H(2)ndca under the ammoniacal condition. It has been structurally characterized by element analysis, IR and X-ray single-crystal diffraction. The bmimb acts as bidentate ligand, and the ndca ligand adopts two different coordination modes in 1, which are mu(4)-eta(1):eta(1):eta(1):eta(1) and mu(2)-eta(1):eta(0):eta(1):eta(0), respectively. Coordination of Ag(I) ions with bmimb and ndca ligands produces two different 1D chains, which is attributed to the different coordination modes of the ndca ligand, indicating the ndca ligand plays an important role in the formation of the diverse 1D chains. The complex 1 exhibits photoluminescent emission in the solid state at room temperature. (C) 2012 Elsevier B.V. All rights reserved.; National Natural Science Foundation of China 21021061 21071118 MSTC 2007CB815301 Independent Innovation Foundation of Shandong University 2011GN030 Special Fund for Postdoctoral Innovation Program of Shandong Province 201101007 |
语种 | 英语 |
出版者 | ELSEVIER SCIENCE BV |
内容类型 | 期刊论文 |
源URL | [http://dspace.xmu.edu.cn/handle/2288/13083] ![]() |
专题 | 化学化工-已发表论文 |
推荐引用方式 GB/T 7714 | Fu-Jing Liu,Liu FJ,Di Sun,et al. A novel one-dimensional mixed ligands silver(I) coordination polymer containing two different chains[J],2012. |
APA | Fu-Jing Liu.,刘福静.,Di Sun.,孙頔.,Hong-Jun Hao.,...&郑兰荪.(2012).A novel one-dimensional mixed ligands silver(I) coordination polymer containing two different chains.. |
MLA | Fu-Jing Liu,et al."A novel one-dimensional mixed ligands silver(I) coordination polymer containing two different chains".(2012). |
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