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	Direct electrochemical synthesis of metal alkoxides
	Chu, DB ; Chu DB(褚道葆) ; Zhou, XF ; Zhou XF(周幸福) ; Lin, CJ ; Lin CJ(林昌健) ; Tan, JG ; Tan JG(谭建光)
	2000
关键词	organic electrosynthesis metal alkoxides cyclic voltammetry FTIR sol-gel
英文摘要	The direct electrochemical synthesis of metal alkoxides [Ti(OEt)(4), Ti(OPr-i)(4), Ti(OBu)(4), Ti(OEt)(2)(acac), Cu(OEt)(2), Cu(OBu)(2), Mg(OEt)(2) and Ni(OEt)(2)] were studied by anode dissolution of metals in absolute ethanol in the presence of a conductive additives.. The anodic behaviour of Ti electrode in ethanol was investigated by using cyclic voltammetry(CV). These metal alkoxides were characterized by FTIR spectra, The results show that direct electrochemical synthesis of metal alkoxides have a high current efficiency and electrolysis yield. These alkoxides have a high purity and can be directly used as the precursor of nanosize oxides prepared by sol-gel procedure, The anodic behaviour of Ti electrode in alcohol is markedly the feature of the pitting corrosion. The passivation of Ti anode would occur in the presence of trace water.
语种	中文
出版者	HIGHER EDUCATION PRESS
内容类型	期刊论文
源URL	[http://dspace.xmu.edu.cn/handle/2288/13059]
专题	化学化工－已发表论文
推荐引用方式 GB/T 7714	Chu, DB,Chu DB,Zhou, XF,et al. Direct electrochemical synthesis of metal alkoxides[J],2000.
APA	Chu, DB.,褚道葆.,Zhou, XF.,周幸福.,Lin, CJ.,...&谭建光.(2000).Direct electrochemical synthesis of metal alkoxides..
MLA	Chu, DB,et al."Direct electrochemical synthesis of metal alkoxides".(2000).

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