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A novel combined electrochemical oscillator from cathode and anode in the IO3-/Fe(CN)(6)(4-) system
Li, Z ; Chen, K ; Zeng, Y ; Yao, SZ ; Zhou, SM ; Zhou SM(周绍民)
2000-05-03
关键词electrochemical oscillations potential oscillations current oscillations coupling oscillator IO3- reduction Fe(CN)(6)(4-) oxidation
英文摘要Experimental studies have been performed for the simultaneous potential or current oscillations occurring both on cathode and anode in the IO3-/Fe(CN)(6)(4-) system. The combined oscillator exhibits very different behavior from that of the individual oscillators on each electrode owing to the different waveforms and incommensurate oscillating frequencies of the individual oscillators. The potential oscillation of the combined oscillator is essentially a sum of those of the individual oscillators for the mixed system, whereas the sum coming from the single systems is slightly different, mainly due to the difference in ionic strength between the single system and the mixed system. The separate current oscillators also seem to interfere with each other, probably through the restricted distribution of the applied voltage in both electrodes and the ohmic drop in addition to the effect of ionic strength (C) 2000 Elsevier Science S.A. All rights reserved.
语种英语
出版者ELSEVIER SCIENCE INC
内容类型期刊论文
源URL[http://dx.doi.org/10.1016/S1388-2481(00)00009-6]  
专题化学化工-已发表论文
推荐引用方式
GB/T 7714
Li, Z,Chen, K,Zeng, Y,et al. A novel combined electrochemical oscillator from cathode and anode in the IO3-/Fe(CN)(6)(4-) system[J],2000.
APA Li, Z,Chen, K,Zeng, Y,Yao, SZ,Zhou, SM,&周绍民.(2000).A novel combined electrochemical oscillator from cathode and anode in the IO3-/Fe(CN)(6)(4-) system..
MLA Li, Z,et al."A novel combined electrochemical oscillator from cathode and anode in the IO3-/Fe(CN)(6)(4-) system".(2000).
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