QQ客服 官方微博 反馈留言

	Hydroboration of C(100) surface, fullerene, and the sidewalls of single-wall carbon nanotubes with borane
	Long, LS ; Long LS(龙腊生) ; Lu, X ; Lv X(吕鑫) ; Tian, F ; Zhang, QE ; Zhang QE(张乾二)
	2003-05-07
英文摘要	Hydroboration of three allotropes of carbon, i.e., diamond (100) surface, [60]fullerene, and single-wall carbon nanotubes (SWNTs), with borane (BH3) has been explored by means of quantum chemical calculations. The calculations predicted that the hydroboration Of C-60 and the C(100)-2 x 1 surface occurs readily, whereas the hydroboration of the sidewall of an armchair (5,5) SWNT is thermoneutral with a barrier height of 11.5 kcal/mol. This suggests that sidewall hydroboration, if viable, would be highly reversible on the (5,5) SWNT. The as-hydroborated carbonous materials can be good starting points for further chemical modification and manipulation of these carbonous materials, given the abundant chemistry of organoboranes.
语种	英语
出版者	AMER CHEMICAL SOC
内容类型	期刊论文
源URL	[http://dx.doi.org/doi:10.1021/jo034395r]
专题	化学化工－已发表论文
推荐引用方式 GB/T 7714	Long, LS,Long LS,Lu, X,et al. Hydroboration of C(100) surface, fullerene, and the sidewalls of single-wall carbon nanotubes with borane[J],2003.
APA	Long, LS.,龙腊生.,Lu, X.,吕鑫.,Tian, F.,...&张乾二.(2003).Hydroboration of C(100) surface, fullerene, and the sidewalls of single-wall carbon nanotubes with borane..
MLA	Long, LS,et al."Hydroboration of C(100) surface, fullerene, and the sidewalls of single-wall carbon nanotubes with borane".(2003).

个性服务

查看访问统计

相关权益政策

暂无数据

收藏/分享

除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。