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A tri-layer structure consisting of novel heptacobaltate clusters and single cobalt centers bridged by 5-tert-butyl isophthalate
Chen, Li-Juan(Fujian Normal Univ, Coll Chem & Mat) ; Su, Jiang-Bo(Fujian Normal Univ, Coll Chem & Mat) ; Huang, Rong-Bin ; Huang RB(黄荣彬) ; Lin, Shen(Fujian Normal Univ, Coll Chem & Mat) ; Yang, Ming-Xing(Fujian Normal Univ, Coll Chem & Mat) ; Huang, Hua(Fujian Normal Univ, Coll Chem & Mat)
2011-07-20
英文摘要A 2D tri-layer compound {[Co(8)(tbip)(6)(H(2)O)(9)(OH)(4)]center dot 12(H(2)O)}(n) (1) (H(2)tbip = 5-tert-butyl isophthalic acid) consisting of novel heptacobaltate clusters and single cobalt centers bridged by tbip(2-) ligands has been hydrothermally synthesized. The complex represents a rare example of a homometallic coordination polymer built up from both heptanuclear metal clusters and single metal centers simultaneously. The magnetic investigation reveals that the complex exhibits the overall predominance of antiferromagnetic coupling between magnetic centers.; National Natural Science Foundation of China[20771024, 21051003]; Natural Science Foundation of Fujian Province[2008I0013]
语种英语
出版者ROYAL SOC CHEMISTRY
内容类型期刊论文
源URL[http://dx.doi.org/doi:10.1039/c1dt10723b]  
专题化学化工-已发表论文
推荐引用方式
GB/T 7714
Chen, Li-Juan,Su, Jiang-Bo,Huang, Rong-Bin,et al. A tri-layer structure consisting of novel heptacobaltate clusters and single cobalt centers bridged by 5-tert-butyl isophthalate[J],2011.
APA Chen, Li-Juan.,Su, Jiang-Bo.,Huang, Rong-Bin.,黄荣彬.,Lin, Shen.,...&Huang, Hua.(2011).A tri-layer structure consisting of novel heptacobaltate clusters and single cobalt centers bridged by 5-tert-butyl isophthalate..
MLA Chen, Li-Juan,et al."A tri-layer structure consisting of novel heptacobaltate clusters and single cobalt centers bridged by 5-tert-butyl isophthalate".(2011).
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