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	Novel Chiral PNNP-Ru Complexes: Synthesis and Application in Asymmetric Transfer Hydrogenation of Ketones
	Cheng, Zhi-bo ; Yu, Shen-luan ; Li, Yan-yun ; Dong, Zhen-rong ; Sun, Guo-song（Guangxi Res Inst Chem Ind） ; Huang, Ke-lin（Guangxi Res Inst Chem Ind） ; Gao, Jing-xing ; Gao JX(高景星)
	2011
关键词	Chiral PNNP ligand Ru complex Asymmetric transfer hydrogenation Aromatic ketone
英文摘要	The efficient catalytic systems generated in situ from RuCl(2)(PPh(3))(3) and chiral ligands N,N-bis[2-(di-o-tolylphosphino)-benzyl]cyclohexane-1,2-diamine(2) were employed for asymmetric transfer hydrogenation of aromatic ketones, giving the corresponding optically active alcohols with high activities(up to 99% conversion) and excellent enantioselectivities(up to 96% e.e.) undcr mild conditions. The chiral ruthenium(II) complex (R,R)-3 has been prepared and characterized by NMR and X-ray crystallography.; National Natural Science Foundation of China[20423002, 20703034]; Natural Science Foundation of Fujian Province of China[2008J0235]; Natural Science Foundation of Guangxi Province of China[0991016]
语种	中文
出版者	HIGHER EDUCATION PRESS
内容类型	期刊论文
源URL	[http://dspace.xmu.edu.cn/handle/2288/11750]
专题	化学化工－已发表论文
推荐引用方式 GB/T 7714	Cheng, Zhi-bo,Yu, Shen-luan,Li, Yan-yun,et al. Novel Chiral PNNP-Ru Complexes: Synthesis and Application in Asymmetric Transfer Hydrogenation of Ketones[J],2011.
APA	Cheng, Zhi-bo.,Yu, Shen-luan.,Li, Yan-yun.,Dong, Zhen-rong.,Sun, Guo-song.,...&高景星.(2011).Novel Chiral PNNP-Ru Complexes: Synthesis and Application in Asymmetric Transfer Hydrogenation of Ketones..
MLA	Cheng, Zhi-bo,et al."Novel Chiral PNNP-Ru Complexes: Synthesis and Application in Asymmetric Transfer Hydrogenation of Ketones".(2011).

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