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A dinuclear zinc complex with (E)-4-dimethylamino-N '-(2-hydroxybenzylidene)benzohydrazide
Ma, Jie ; Fan, Wei-Zhen ; Lin, Li-Rong ; Lin LR(林丽榕)
2011-05
英文摘要The title compound, bis[mu-(E)-2-({2-[4-(dimethylamino)-benzoyl]hydrazinylidene} methyl) phenolato]bis[formatozinc], [Zn(2)(C(16)H(16)N(3)O(2))(2)(CHO(2))(2)], is a dinuclear Zn(II) complex containing two Zn(II) cations, two monovalent anions of a Schiff base ligand, 4-dimethylamino-N'-(2-hydroxybenzylidene)benzohydrazide (L), and two formate ions. Each Zn(II) atom chelates with the hydroxy O atom of salicylaldehyde, the imine N atom, the carbonyl O atom, the formate carboxylate O atom and the hydroxy O atom of the salicylaldehyde moiety in a symmetry-related unit. The five-coordinate Zn(II) atoms form a dimeric centrosymmetric unit with a central parallelepiped Zn(2)O(2) core and parallel faces derived from the Schiff base ligands. The crystal packing is stabilized by intermolecular N-H center dot center dot center dot O hydrogen bonds between the amide N atom and the formate carboxylate O atom.; Natural Science Foundation of Fujian Province[2009S0063, 2010J01048]
语种英语
出版者WILEY-BLACKWELL
内容类型期刊论文
源URL[http://dx.doi.org/doi:10.1107/S1600536811014462]  
专题化学化工-已发表论文
推荐引用方式
GB/T 7714
Ma, Jie,Fan, Wei-Zhen,Lin, Li-Rong,et al. A dinuclear zinc complex with (E)-4-dimethylamino-N '-(2-hydroxybenzylidene)benzohydrazide[J],2011.
APA Ma, Jie,Fan, Wei-Zhen,Lin, Li-Rong,&林丽榕.(2011).A dinuclear zinc complex with (E)-4-dimethylamino-N '-(2-hydroxybenzylidene)benzohydrazide..
MLA Ma, Jie,et al."A dinuclear zinc complex with (E)-4-dimethylamino-N '-(2-hydroxybenzylidene)benzohydrazide".(2011).
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