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	Synthesis of novel chiral N, P-containing multidentate ligands and their applications in asymmetric transfer hydrogenation
	Yu, Shen Luan ; Li, Yan Yun ; Dong, Zhen Rong ; Zhang, Juan Ni ; Li, Qi ; Gao, Jing Xing ; Gao JX(高景星)
	2011-07-29
关键词	Chiral multidentate aminophosphine ligand Iridium complex Propiophenone Asymmetric transfer hydrogenation
英文摘要	Novel chiral PN(4)-type multidentate aminophosphine ligands have been successfully synthesized by Schiff-base condensation of bis(o-formylphenyl)phenylphosphane and various chiral amino-sulfonamides. Their structures were fully characterized by IR, EIMS and NMR. The catalytic systems, prepared in situ from the multidentate ligands and iridium(I) complexes, showed high activity in asymmetric transfer hydrogenation of propiophenone in 2-propanol solution, leading to corresponding optical alcohol with up to 75% ee. (C) 2011 Yan Yun Li and Jing Xing Gao. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.; Natural Science Foundation of China[20423002, 20703034]; Natural Science Foundation of Fujian Province of China[2008J0235]
语种	英语
出版者	ELSEVIER SCIENCE INC
内容类型	期刊论文
源URL	[http://dx.doi.org/doi:10.1016/j.cclet.2011.05.033]
专题	化学化工－已发表论文
推荐引用方式 GB/T 7714	Yu, Shen Luan,Li, Yan Yun,Dong, Zhen Rong,et al. Synthesis of novel chiral N, P-containing multidentate ligands and their applications in asymmetric transfer hydrogenation[J],2011.
APA	Yu, Shen Luan.,Li, Yan Yun.,Dong, Zhen Rong.,Zhang, Juan Ni.,Li, Qi.,...&高景星.(2011).Synthesis of novel chiral N, P-containing multidentate ligands and their applications in asymmetric transfer hydrogenation..
MLA	Yu, Shen Luan,et al."Synthesis of novel chiral N, P-containing multidentate ligands and their applications in asymmetric transfer hydrogenation".(2011).

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