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	Characterization of an unprecedented (ethanol)(4) cluster in a novel photoluminescent silver(I) coordination polymer
	Sun, Di ; Li, Yun-Hua ; Li SH(李顺华) ; Liu, Fu-Jing ; Hao, Hong-Jun ; Huang, Rong-Bin ; Huang RB(黄荣彬) ; Zheng, Lan-Sun ; Zheng LS(郑兰荪)
	2011-09-05
关键词	Silver(I) 2,4-Diamino-6-methyl-1,3,5-triazine Naphthalene-1,4-dicarboxylic acid Ethanol cluster Crystal structure
英文摘要	An unprecedented (ethanol)4 cluster is observed in a photoluminescent silver(I) coordination polymer host, [Ag(2) (dmt)(2)(nda)center dot 2EtOH](n) (1, dmt=2,4-diamino-6-methyl-1,3,5-triazine, H(2)nda=naphthalene-1,4-dicarboxylic acid, EtOH = ethanol). In 1, two pairs of symmetry-related ethanol molecules are hydrogen bonded with each other by O-H center dot center dot center dot O hydrogen bonds to form a R(4)(4)(8) hydrogen bond motif where all the ethanol molecules are proton acceptor and proton donor at the same time. The thermal stability and luminescent behavior of 1 were also discussed. (C) 2011 Elsevier B.V. All rights reserved.; National Natural Science Foundation of China[21021061, 21071118]; MSTC[2007CB815301]
语种	英语
出版者	ELSEVIER SCIENCE BV
内容类型	期刊论文
源URL	[http://dx.doi.org/doi:10.1016/j.inoche.2011.09.002]
专题	化学化工－已发表论文
推荐引用方式 GB/T 7714	Sun, Di,Li, Yun-Hua,Li SH,et al. Characterization of an unprecedented (ethanol)(4) cluster in a novel photoluminescent silver(I) coordination polymer[J],2011.
APA	Sun, Di.,Li, Yun-Hua.,李顺华.,Liu, Fu-Jing.,Hao, Hong-Jun.,...&郑兰荪.(2011).Characterization of an unprecedented (ethanol)(4) cluster in a novel photoluminescent silver(I) coordination polymer..
MLA	Sun, Di,et al."Characterization of an unprecedented (ethanol)(4) cluster in a novel photoluminescent silver(I) coordination polymer".(2011).

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