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	Separation and Characterization of C70(C14H10) and C70(C5H6) from an Acetylene–Benzene–Oxygen Flame
	Qun-Hong Weng ; Weng QH(翁群红) ; Qiao He ; He Q(何桥) ; Di Sun ; Sun D(孙頔) ; Hui-Ying Huang ; Huang HY(黄慧英) ; Su-Yuan Xie ; Xie SY(谢素原) ; Xin Lu ; Lv X(吕鑫) ; Rong-Bin Huang ; Huang RB(黄荣彬) ; Lan-Sun Zheng ; Zheng LS(郑兰荪)
	2011-06-09
关键词	POLYCYCLIC AROMATIC-HYDROCARBONS FULLERENIC NANOSTRUCTURES COMBUSTION SYNTHESIS CHEMICAL-SYNTHESIS DIFFUSION FLAME C-60 C-70 CARBON CHLOROFORM CHEMISTRY
英文摘要	syxie@xmu.edu.cn, xinlu@xmu.edu.cn; Although derivatives of fullerenes are prevalent in the fullerene-producing flame, the chemistry of these derivatives has rarely been discussed in the previous literature. In this paper, two D(Sh)-C(70) derivatives, C(70)(C(14)H(10)) and C(70)(C(5)H(6)), were isolated from the soot of an acetylene benzene combustion. On the basis of detailed MS, NMR, IR, and UV/vis analyses in combination with DFT calculations, the cycloadduct structures of C(70)(C(14)H(10)) and C(20)(C(5)H(6)) were identified. Both the anthracene (C(14)H(10)) and the cyclopentadiene (C(5)H(6)) adducts, supposed as the intermediate species produced during the combustion process, were characterized to bond at a [6,6] ring junction at the end of the olivary C(70) cage. The present work exemplifies the capture of possible intermediates by the C(70) fullerene from the flame and thus provides insight into the mechanism responsible for the formation of fullerene-containing soot.; NSFC 21031004 ,20973137,21021061 973 projects 2007CB815301 ,2007CB815307
语种	英语
出版者	AMER CHEMICAL SOC
内容类型	期刊论文
源URL	[http://dspace.xmu.edu.cn/handle/2288/10681]
专题	化学化工－已发表论文
推荐引用方式 GB/T 7714	Qun-Hong Weng,Weng QH,Qiao He,et al. Separation and Characterization of C70(C14H10) and C70(C5H6) from an Acetylene–Benzene–Oxygen Flame[J],2011.
APA	Qun-Hong Weng.,翁群红.,Qiao He.,何桥.,Di Sun.,...&郑兰荪.(2011).Separation and Characterization of C70(C14H10) and C70(C5H6) from an Acetylene–Benzene–Oxygen Flame..
MLA	Qun-Hong Weng,et al."Separation and Characterization of C70(C14H10) and C70(C5H6) from an Acetylene–Benzene–Oxygen Flame".(2011).

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