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	Asymmetric dinuclear hydroxyl and ethoxyl citrato dioxovanadates(V)
	Chen, Can-Yu ; Zhou, Zhao-Hui ; Zhou CH(周朝晖) ; Mao, Shao-Yu ; Mao SY(毛少瑜) ; Wan, Hui-Lin ; Wan HL(万惠霖)
	2007-07
关键词	citrate citric vanadium vanadate hydroxy ethoxy crystal structure
英文摘要	Asymmetric citrato dioxovanadates(V), [Hneo](4)[V2O4(R-Hcit)(OH)][V2O4(S-Hcit)(OH)] center dot 4H(2)O (1) and [Ni(phen)(3)](2)[V2O4(R-Hcit)(OC2H5)][V2O4(S- Hcit)(OC2H5)] center dot 4H(2)O (2) and (H(4)cit citric acid, neo 2,9-dimethyl-1,10-phenanthroline, phen 1,10-phenanthroline) are isolated with the help of large counterions. Structural analyses of complexes 1 and 2 show that vanadium atoms are coordinated by tridentate citrate ligand and hydroxy or ethoxy groups, respectively. The insertions of hydroxy and ethoxy groups give new examples of the mixed RO-bridges for vanadium-citrate complexes.
语种	英语
出版者	TAYLOR & FRANCIS LTD
内容类型	期刊论文
源URL	[http://dx.doi.org/doi:10.1080/00958970601029420]
专题	化学化工－已发表论文
推荐引用方式 GB/T 7714	Chen, Can-Yu,Zhou, Zhao-Hui,Zhou CH,et al. Asymmetric dinuclear hydroxyl and ethoxyl citrato dioxovanadates(V)[J],2007.
APA	Chen, Can-Yu.,Zhou, Zhao-Hui.,周朝晖.,Mao, Shao-Yu.,毛少瑜.,...&万惠霖.(2007).Asymmetric dinuclear hydroxyl and ethoxyl citrato dioxovanadates(V)..
MLA	Chen, Can-Yu,et al."Asymmetric dinuclear hydroxyl and ethoxyl citrato dioxovanadates(V)".(2007).

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