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	Synthesis, characterization and solid-state CD spectra of the chiral bisferrocenyl ligands
	Huang Xiao-Qing ; Huang XQ(黄小青) ; Xuan Wei-Min ; Xuan WM(宣为民) ; Chen Lei-Qi ; Chen LQ(陈雷奇) ; Zhang Hui ; Zhang H(章慧) ; Gao Jing-Xing ; Gao JX(高景星)
	2007
关键词	synthesis chirality bisferrocenyl ligand solid-state circular dichroism spectroscopy
英文摘要	A pair of novel chiral tetradentate bisferrocenyl ligands [N,N '-bisferrocenyimethyl-N,N '-bis(2hydroproxypyl)- (1R, 2R)-1,2-diphenylethane-diamine(5R), N,N '-bisferrocenylmethyl-N,N '-bis(2-hydroxypropyl)-(1S, 2S)-1,2-diphenylethane diamine (5S)] were synthesized from ferrocenylcarboxaldehyde (1) and chiral 1,2-diphenylethanediamine (2R or 2S) followed by the reduction of the Schiff bases with NaBH4 and subsequent N-alkylation with 1,2-propyleneoxide. All the chiral products (3R-5S) were charactered by elemental analysis, infrared (IR), H-1 nuclear magnetic resonance (H-1 NMR), ultraviolet-visible (UV-Vis) and solid-state circular dichroism (CD) spectra. The solidstate CD spectra reveal that the chiral characteristics of 5R (or 5S) are quite similar with 4R (or 4S) and it is also notable that there are some differences between 5R (or 5S) and 3R (or 3S).
语种	英语
出版者	PEKING UNIV PRESS
内容类型	期刊论文
源URL	[http://dx.doi.org/doi:CNKI:SUN:WLHX.0.2007-12-007]
专题	化学化工－已发表论文
推荐引用方式 GB/T 7714	Huang Xiao-Qing,Huang XQ,Xuan Wei-Min,et al. Synthesis, characterization and solid-state CD spectra of the chiral bisferrocenyl ligands[J],2007.
APA	Huang Xiao-Qing.,黄小青.,Xuan Wei-Min.,宣为民.,Chen Lei-Qi.,...&高景星.(2007).Synthesis, characterization and solid-state CD spectra of the chiral bisferrocenyl ligands..
MLA	Huang Xiao-Qing,et al."Synthesis, characterization and solid-state CD spectra of the chiral bisferrocenyl ligands".(2007).

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