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	Influence of aminopyrimidyl derivatives on the supramolecular architectures and abundant nonvalent interactions of silver 5-nitroisophthalate coordination polymers
	Sun, Di ; Luo, Geng-Geng ; Zhang, Na ; Wei, Zhan-Hua ; Yang, Cheng-Feng ; Xu, Qin-Juan ; Huang, Rong-Bin ; Huang RB(黄荣彬) ; Zheng, Lan-Sun ; Zheng LS(郑兰荪)
	2010-01
关键词	Silver(I) 2-Aminopyrimidine Lone-pair center dot center dot center dot pi Coordination polymer Nonvalent interactions
英文摘要	Two 5-nitroisophthalate silver(I) coordination polymers with 2-aminopyrimidyl derivatives, namely [Ag-2(apym)(1.5)(nipa)center dot H2O](n) (1) and [Ag-2(dmapym)(2)(nipa)](n) (2) were synthesized and characterized by single-crystal X-ray analysis (apym = 2-aminopyrimidine, dmapym = 2-amino-4,6-dimethylprimidine, H(2)nipa = 5-nitroisophthalic acid). Complex 1 possesses a one-dimensional (1D) structure built from rhombic [Ag-4(apym)(2)(nipa)(2)] second building units (SBUs). The uncoordinated O-nitro is involved in the significant lone-pair (Ip)center dot center dot center dot pi interaction with the benzene ring of nipa. Complex 2 possesses a two-dimensional (20) structure in which dmapym ligands show two different coordination modes, monodentate and bidentate, respectively. Moreover, 2 shows abundant nonvalent interactions, such as Ip(O-carboxyl)center dot center dot center dot pi, pi center dot center dot center dot pi, C-H center dot center dot center dot pi interactions and hydrogen-bonding simultaneously. 1 and 2 also exhibit diverse structure motifs due to the effects of substituent methyl groups. The photoluminescence properties of these complexes also were examined. (C) 2010 Elsevier B.V. All rights reserved.; National Natural Science Foundation of China [20721001]; 973 Project [2007CB815301]; MSTC ; National Science Fund of China for Fostering Talents in Basic Science [J0630429]
语种	英语
出版者	ELSEVIER SCIENCE BV
内容类型	期刊论文
源URL	[http://dx.doi.org/doi:10.1016/j.molstruc.2010.01.003]
专题	化学化工－已发表论文
推荐引用方式 GB/T 7714	Sun, Di,Luo, Geng-Geng,Zhang, Na,et al. Influence of aminopyrimidyl derivatives on the supramolecular architectures and abundant nonvalent interactions of silver 5-nitroisophthalate coordination polymers[J],2010.
APA	Sun, Di.,Luo, Geng-Geng.,Zhang, Na.,Wei, Zhan-Hua.,Yang, Cheng-Feng.,...&郑兰荪.(2010).Influence of aminopyrimidyl derivatives on the supramolecular architectures and abundant nonvalent interactions of silver 5-nitroisophthalate coordination polymers..
MLA	Sun, Di,et al."Influence of aminopyrimidyl derivatives on the supramolecular architectures and abundant nonvalent interactions of silver 5-nitroisophthalate coordination polymers".(2010).

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