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	Homochiral Supramolecular Compounds Constructed from Amino Acid Derivatives: Syntheses, Structures, Chiroptical, and Photoluminescence Properties
	Li, Xinfa（Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem） ; Liu, Tianfu（Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem） ; Hu, Bing（Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem） ; Li, Guoliang（Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem） ; Zhang, Hui ; Zhang H(章慧) ; Cao, Rong（Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem）
	2010-06
英文摘要	Recrystallization of enantiopure amino acid derivatives N-(2-pyridylmethyl)-alanine in MeOH resulted in high quality crystals of compounds 1 (L-Hpala) and 2 (D-Hpala). Self-assembly of L- or D-Hpala with Zn(CH3CO2)(2)center dot 2H(2)O in MeOH in a ratio of 2:1 produced two enantiopure neutral mononuclear complexes [Zn(L-pala)(2)]center dot H2O (3) and [Zn(D-pala)(2)] center dot H2O (4) with almost quantitative yields. X-ray single crystal diffraction analyses reveal that they are two-dimensional undulate homochiral supramolecular structures. Circular dichroism (CD) spectra confirm that 1 and 2, 3 and 4 are one pair of enantiomers, respectively. [Cu-1.5(spp)(bpy)(1.5)(H2O)(2)(NO3)](NO3)center dot 4H(2)O (5) was prepared by the self-assembly of Cu(NO3)(2)center dot 3H(2)O pala(-), and 4,4'-dipyridyl (bpy) in a H2O-EtOH mixture involving the in situ formation of a Schiff base ligand N-(2-pyridylmethyl)-pyruvic acid (spp(-)). Compound 5 crystallized in the cent rosymmetric C2/c space group. It features a three-dimensional supramolecular network by interconnection of an antenna-shaped Cu-containing sheet and a hydrogen bonded supramolecular layer in the alternate ...ABAB... stacking mode. The solid-state photoluminescence properties of 1 and 3 were also investigated.; 973 Program [2006CB932903, 200703815303]; NSFC [20873151, 20731005]; NSF of Fujian Province [2006F3134]; CAS
语种	英语
出版者	AMER CHEMICAL SOC
内容类型	期刊论文
源URL	[http://dx.doi.org/doi:10.1021/cg100163g]
专题	化学化工－已发表论文
推荐引用方式 GB/T 7714	Li, Xinfa,Liu, Tianfu,Hu, Bing,et al. Homochiral Supramolecular Compounds Constructed from Amino Acid Derivatives: Syntheses, Structures, Chiroptical, and Photoluminescence Properties[J],2010.
APA	Li, Xinfa.,Liu, Tianfu.,Hu, Bing.,Li, Guoliang.,Zhang, Hui.,...&Cao, Rong.(2010).Homochiral Supramolecular Compounds Constructed from Amino Acid Derivatives: Syntheses, Structures, Chiroptical, and Photoluminescence Properties..
MLA	Li, Xinfa,et al."Homochiral Supramolecular Compounds Constructed from Amino Acid Derivatives: Syntheses, Structures, Chiroptical, and Photoluminescence Properties".(2010).

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