QQ客服 官方微博 反馈留言

	Ferromagnetic interactions in a bis(mu-end-on azido)cobalt(II) linear trimer
	Xun Lin ; Lin X(林洵) ; Jun Tao ; Tao J(陶军) ; Rong-Bin Huang ; Huang RB(黄荣彬) ; Lan-Sun Zheng ; Zheng LS(郑兰荪)
	2009-02
关键词	Trinuclear compound Azide Ferromagnetic interaction Cobalt(II)
英文摘要	通讯作者地址: Tao, J (通讯作者), Xiamen Univ, Dept Chem, Coll Chem & Chem Engn, State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Peoples R China 地址: 1. Xiamen Univ, Dept Chem, Coll Chem & Chem Engn, State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Peoples R China 2. Zhangzhou Inst Technol, Dept Food & Bioengn, Zhangzhou, Fujian Peoples R China; A linear trinuclear Co(II) compound, [Co-3(mu(1,1)-N-3)(4)(N-3)(2)(H2O)(2)(bpbp)(2)] center dot 2H(2)O (1, bpbp = 3,3'-bis-Dimethytamino-1,1'-pyridine-2,6-diyl-bispropenone), is reported. The central Co(II) ion is bridged to Co(II) ions on both sides by four end-on azide (mu(1,1)-N-3(-)) ligands resulting in a centrosymmetric trimer with adjacent Co center dot center dot center dot Co distance of 3.233 angstrom. Each Co(II) ion possesses distorted octahedral geometry, the central one is coordinated by two aqua ligands and four mu(1,1)-N-3(-) nitrogen atoms and each terminal Co(II) is coordinated by two mu(1,1)-N-3(-) nitrogen atoms, one terminal N-3(-) nitrogen atom and capped by terminal tridentate bpbp ligand. Variable temperature magnetic studies indicate ferromagnetic coupling between adjacent Co(II) ions within the trimer. Crown Copyright (C) 2008 Published by Elsevier B.V. All rights reserved.
语种	英语
出版者	ELSEVIER SCIENCE BV
内容类型	期刊论文
源URL	[http://dspace.xmu.edu.cn/handle/2288/3451]
专题	化学化工－已发表论文
推荐引用方式 GB/T 7714	Xun Lin,Lin X,Jun Tao,et al. Ferromagnetic interactions in a bis(mu-end-on azido)cobalt(II) linear trimer[J],2009.
APA	Xun Lin.,林洵.,Jun Tao.,陶军.,Rong-Bin Huang.,...&郑兰荪.(2009).Ferromagnetic interactions in a bis(mu-end-on azido)cobalt(II) linear trimer..
MLA	Xun Lin,et al."Ferromagnetic interactions in a bis(mu-end-on azido)cobalt(II) linear trimer".(2009).

个性服务

查看访问统计

相关权益政策

暂无数据

收藏/分享

除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。