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	Low dimensional metal-organic frameworks (MOFs) constructed from simple aminopyrimidyl derivatives: From oligomer to single neutral zigzag chain and doubly ionic chains
	Geng-Geng Luo ; Luo GG(骆耿耿) ; Di Sun ; Sun D(孙頔) ; Na Zhang ; Zhang N(张娜) ; Rong-Bin Huang ; Huang RB(黄荣彬) ; Lan-Sun Zheng ; Zheng LS(郑兰荪)
	2009-12-16
关键词	Silver 2-Aminopyrimidine derivatives Low dimensional Anion-pi interactions Hydrogen bonds
英文摘要	通讯作者地址: Huang, RB (通讯作者), Xiamen Univ, Dept Chem, Coll Chem & Chem Engn, Xiamen 361005, Peoples R China 地址: 1. Xiamen Univ, Dept Chem, Coll Chem & Chem Engn, Xiamen 361005, Peoples R China 2. Xiamen Univ, State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Peoples R China; Three low dimensional silver(1)complexes of the formula [Ag(L-1)][Ag(L-1)(CF3SO3)(2)](1), [Ag-2(L-2)(3)(CF3SO3)(2)] (2), and [Ag(L-2)(CF3CO2)](n) (3), where L-1 = 2-amino-4-methoxy-6-methylpyrimidine and L-2 = 2-amino-4,6-dimethoxypyrimidine, have been synthesized and structurally characterized by single-crystal X-ray diffraction. Complex 1 is a new rarely reported Ag-1 one dimensional (1D)coordination polymer, which consists of independently cat ionic and anionic doubly chains The hydrogen bonds and Ag 0 weak interactions between chains extend 1 into two dimensional (2D) interlayer networks Complex 2 is a simple oligomer and two neighbored oligomers interact to produce a supramolecular dimer through hydrogen bonds, weak Ag N-(amino) interactions and anion-pi interactions Complex 3 displays 1D neutral zigzag chain which is structurally very similar to the 1D cationic one in 1, if neglecting counter anions in the former The adjacent chains in 3 are further interlinked to generate 1D ladder structure via Ag 0 weak interactions and N-H O intermolecular hydrogen bonds. The results reveal that the nature of the Counter anions and organic ligands all has great impact on the structure of the complexes The luminescence properties of the synthesized silver complexes were also investigated in the solid stale at room temperature.; National Natural Science Foundation of China 20721001 MSTC 20070815301 Chinese Government Scholarship
语种	英语
出版者	ELSEVIER SCIENCE BV
内容类型	期刊论文
源URL	[http://dspace.xmu.edu.cn/handle/2288/3446]
专题	化学化工－已发表论文
推荐引用方式 GB/T 7714	Geng-Geng Luo,Luo GG,Di Sun,et al. Low dimensional metal-organic frameworks (MOFs) constructed from simple aminopyrimidyl derivatives: From oligomer to single neutral zigzag chain and doubly ionic chains[J],2009.
APA	Geng-Geng Luo.,骆耿耿.,Di Sun.,孙頔.,Na Zhang.,...&郑兰荪.(2009).Low dimensional metal-organic frameworks (MOFs) constructed from simple aminopyrimidyl derivatives: From oligomer to single neutral zigzag chain and doubly ionic chains..
MLA	Geng-Geng Luo,et al."Low dimensional metal-organic frameworks (MOFs) constructed from simple aminopyrimidyl derivatives: From oligomer to single neutral zigzag chain and doubly ionic chains".(2009).

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