C-H center dot center dot center dot pi interaction and N center dot center dot center dot H-O hydrogen bonding in the chair-like p-tert-butylcalix[8]arene complex including four pyridine molecules | |
RONG-BIN HUANG ; Huang RB(黄荣彬) ; NAN-FENG ZHENG ; Zheng NF(郑南峰) ; SU-YUAN XIE ; Xie SY(谢素原) ; LAN-SUN ZHENG ; Zheng LS(郑兰荪) | |
2001-06 | |
关键词 | calix[8]arenes hydrogen bonding pyridines supramolecular interaction |
英文摘要 | 通讯作者地址: Zheng, LS (通讯作者), Xiamen Univ, Dept Chem, State Key Lab Phys Chem Solid Sirface, Xiamen 361005, Peoples R China 地址: 1. Xiamen Univ, Dept Chem, State Key Lab Phys Chem Solid Sirface, Xiamen 361005, Peoples R China; Crystal structure analysis shows that the p-tert-butylcalix[8]arene host and its four pyridine guests sit around an inversion center in the P2(1)/c crystal lattice. The monoclinic cell parameters and its volume are: a = 19.617(4), b = 9.912(2), c = 25.178(5) Angstrom, beta = 101.03(3)degrees, V =4805.27(17) Angstrom (3). For Z = 2 and Mw = 1614.18, the calculated density Dcalc = 1.116 g/cm(3). A host calixarene molecule includes four pyridine guests in two different ways: by hydrogen bonding and by possible C-H... pi interaction between the molecules. The hydrogen bonding drives the host macrocycle into a chair-like conformation. |
语种 | 英语 |
出版者 | KLUWER ACADEMIC PUBL |
内容类型 | 期刊论文 |
源URL | [http://dspace.xmu.edu.cn/handle/2288/3140] ![]() |
专题 | 化学化工-已发表论文 |
推荐引用方式 GB/T 7714 | RONG-BIN HUANG,Huang RB,NAN-FENG ZHENG,et al. C-H center dot center dot center dot pi interaction and N center dot center dot center dot H-O hydrogen bonding in the chair-like p-tert-butylcalix[8]arene complex including four pyridine molecules[J],2001. |
APA | RONG-BIN HUANG.,黄荣彬.,NAN-FENG ZHENG.,郑南峰.,SU-YUAN XIE.,...&郑兰荪.(2001).C-H center dot center dot center dot pi interaction and N center dot center dot center dot H-O hydrogen bonding in the chair-like p-tert-butylcalix[8]arene complex including four pyridine molecules.. |
MLA | RONG-BIN HUANG,et al."C-H center dot center dot center dot pi interaction and N center dot center dot center dot H-O hydrogen bonding in the chair-like p-tert-butylcalix[8]arene complex including four pyridine molecules".(2001). |
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