| 官能化噻咯合成研究进展Ⅰ.关环法和环内转换法; Research and progress in synthesis of functionalized siloes Ⅰ. cyclization and metallacycle transfer | |
| 朱林晖 ; 夏海平 ; 丁马太 | |
| 2005-02 | |
| 关键词 | 噻咯 官能团 内向内向型分子内还原关环 环内金属转换 silole functional group endo-endo mode intramolecular reductive cyclization metallacycle transfer |
| 英文摘要 | 噻咯(silole音译)因具有独特的电子结构和光电性能,已成为近年来研究的热点。官能化噻咯作为重要的噻咯衍生物,不仅在有机合成领域占重要地位,而且是建构新型π共轭体系的重要组成部分。本文介绍了官能化噻咯的两种重要合成方法,即炔的内向 内向型分子内还原关环法和环内金属转换法,并对其特点、适用范围及发展方向作了分析和展望。Silole has been t he focus of recent investigations due to it s unique elect ronic st ructures. Functionalized siloles , as an important group of silole derivatives , not only play an important role in organometallic synt hesis , but were the main constit uent s for t he const ruction of π2conjugated compounds. Two important routes to pre2 pare f unctionalized siloles , namely“endo2endo mode int ramolecular reductive cyclization of diynes”and“metalla2 cycle t ransfer”, were reviewed in this paper . The property , application scope and prospect of each met hod are al so discussed.; 国家自然科学基金资助项目(29774019) |
| 语种 | 中文 |
| 出版者 | 重庆仪表材料研究所 |
| 内容类型 | 期刊论文 |
| 源URL | [http://dspace.xmu.edu.cn/handle/2288/3112]  |
| 专题 | 化学化工－已发表论文 |
| 推荐引用方式 GB/T 7714 | 朱林晖,夏海平,丁马太. 官能化噻咯合成研究进展Ⅰ.关环法和环内转换法, Research and progress in synthesis of functionalized siloes Ⅰ. cyclization and metallacycle transfer[J],2005. |
| APA | 朱林晖,夏海平,&丁马太.(2005).官能化噻咯合成研究进展Ⅰ.关环法和环内转换法.. |
| MLA | 朱林晖,et al."官能化噻咯合成研究进展Ⅰ.关环法和环内转换法".(2005). |
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