The graphite arc-discharge in the presence of CCl4: Chlorinated carbon clusters in relation with fullerenes formation | |
Fei Gao ; Gao F(高飞) ; Su-Yuan Xie ; Xie SY(谢素原) ; Zhi-Jie Ma ; Ma ZJ(马志杰) ; Yu-Qi Feng ; 冯钰锜(武汉大学化学系) ; Rong-Bin Huang ; Huang RB(黄荣彬) ; Lan-Sun Zheng ; Zheng LS(郑兰荪) | |
2004 | |
关键词 | Fullerene Carbon clusters Arc discharge Mass spectrometry |
英文摘要 | 通讯作者地址: Xie, SY (通讯作者), Xiamen Univ, Dept Chem, State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Peoples R China 地址: 1. Xiamen Univ, Dept Chem, State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Peoples R China 2. Wuhan Univ, Dept Chem, Wuhan 430072, Peoples R China; The graphite arc-discharge in the atmosphere consisting of CCl4 40 Torr and increasing partial pressure of He from 0 to 300 Torr produced, in addition to carbon species such as graphite and fullerenes C60 and C70, numerous chlorinated carbon clusters (CCCs). The yields of some CCCs, including C6Cl6 (perchlorobenzene), C10Cl8 (perchloronaphthalene), C12Cl8 (perchloroacenaphthylene) and C12Cl8 (isomer II), C14Cl8 (isomer I), C16Cl10 (perchlorofluoranthene), C18Cl10 (isomer I and II), and C20Cl10 (isomer I), correspond well with C60 yields, which may imply these CCCs share the same growth mechanism with fullerenes. Such a yield correlation can be used to distinguish the fullerene precursors from the irrelevant by-products, thus contributes to the mechanistic study of fullerene formation. |
语种 | 英语 |
出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
内容类型 | 期刊论文 |
源URL | [http://dspace.xmu.edu.cn/handle/2288/3099] |
专题 | 化学化工-已发表论文 |
推荐引用方式 GB/T 7714 | Fei Gao,Gao F,Su-Yuan Xie,et al. The graphite arc-discharge in the presence of CCl4: Chlorinated carbon clusters in relation with fullerenes formation[J],2004. |
APA | Fei Gao.,高飞.,Su-Yuan Xie.,谢素原.,Zhi-Jie Ma.,...&郑兰荪.(2004).The graphite arc-discharge in the presence of CCl4: Chlorinated carbon clusters in relation with fullerenes formation.. |
MLA | Fei Gao,et al."The graphite arc-discharge in the presence of CCl4: Chlorinated carbon clusters in relation with fullerenes formation".(2004). |
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