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The graphite arc-discharge in the presence of CCl4: Chlorinated carbon clusters in relation with fullerenes formation
Fei Gao ; Gao F(高飞) ; Su-Yuan Xie ; Xie SY(谢素原) ; Zhi-Jie Ma ; Ma ZJ(马志杰) ; Yu-Qi Feng ; 冯钰锜(武汉大学化学系) ; Rong-Bin Huang ; Huang RB(黄荣彬) ; Lan-Sun Zheng ; Zheng LS(郑兰荪)
2004
关键词Fullerene Carbon clusters Arc discharge Mass spectrometry
英文摘要通讯作者地址: Xie, SY (通讯作者), Xiamen Univ, Dept Chem, State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Peoples R China 地址: 1. Xiamen Univ, Dept Chem, State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Peoples R China 2. Wuhan Univ, Dept Chem, Wuhan 430072, Peoples R China; The graphite arc-discharge in the atmosphere consisting of CCl4 40 Torr and increasing partial pressure of He from 0 to 300 Torr produced, in addition to carbon species such as graphite and fullerenes C60 and C70, numerous chlorinated carbon clusters (CCCs). The yields of some CCCs, including C6Cl6 (perchlorobenzene), C10Cl8 (perchloronaphthalene), C12Cl8 (perchloroacenaphthylene) and C12Cl8 (isomer II), C14Cl8 (isomer I), C16Cl10 (perchlorofluoranthene), C18Cl10 (isomer I and II), and C20Cl10 (isomer I), correspond well with C60 yields, which may imply these CCCs share the same growth mechanism with fullerenes. Such a yield correlation can be used to distinguish the fullerene precursors from the irrelevant by-products, thus contributes to the mechanistic study of fullerene formation.
语种英语
出版者PERGAMON-ELSEVIER SCIENCE LTD
内容类型期刊论文
源URL[http://dspace.xmu.edu.cn/handle/2288/3099]  
专题化学化工-已发表论文
推荐引用方式
GB/T 7714
Fei Gao,Gao F,Su-Yuan Xie,et al. The graphite arc-discharge in the presence of CCl4: Chlorinated carbon clusters in relation with fullerenes formation[J],2004.
APA Fei Gao.,高飞.,Su-Yuan Xie.,谢素原.,Zhi-Jie Ma.,...&郑兰荪.(2004).The graphite arc-discharge in the presence of CCl4: Chlorinated carbon clusters in relation with fullerenes formation..
MLA Fei Gao,et al."The graphite arc-discharge in the presence of CCl4: Chlorinated carbon clusters in relation with fullerenes formation".(2004).
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