AIBN/NaNO_2/FeSO_4.7H_2O存在下苯乙烯本体活性自由基聚合; STUDIED ON LIVING POLYMERIZATION OF STYRENE IN THE PRESENCE OF AIBN/NaNO_2/FeSO_4·7H_2O | |
颜明发 ; 李万利 ; 黄剑莹 ; 林明华 ; 林强 ; 邹友思 | |
2005-01 | |
关键词 | 活性自由基聚合 亚硝酸钠 稳定自由基 living free radical polymertzation NaNO_2 stable free radical |
英文摘要 | [中文文摘]研究了AIBN/NaNO2/FeSO4.7H2O存在下苯乙烯本体聚合行为,发现100℃以上时具有活性聚合特征,AIBN/NaNO2/FeSO4.7H2O配比为1/3/3时分子量多分散性指数控制较好,聚合物分子量多分散性指数在1.1~1.8之间,聚合过程转化率和分子量随时间的增加而增大。[英文文摘]Polymerization of styrene was studied in the presence of AIBN/NaNO_2/FeSO_4·7H_2O in this paper. It is found that polymertzation of styrene is living when temperature is higher than 100 ℃, and when the molar ratio of AIBN/NaNO_2/FeSO_4·7H_2O is 1/3/3, the molecular weight polydispersities are narrower, which is between (1.1) and (1.8). With the increasing of time, the conversion of monomer and the molecular weight of polymer also increase. |
语种 | 中文 |
出版者 | 四川大学 |
内容类型 | 期刊论文 |
源URL | [http://dspace.xmu.edu.cn/handle/2288/3020] ![]() |
专题 | 化学化工-已发表论文 |
推荐引用方式 GB/T 7714 | 颜明发,李万利,黄剑莹,等. AIBN/NaNO_2/FeSO_4.7H_2O存在下苯乙烯本体活性自由基聚合, STUDIED ON LIVING POLYMERIZATION OF STYRENE IN THE PRESENCE OF AIBN/NaNO_2/FeSO_4·7H_2O[J],2005. |
APA | 颜明发,李万利,黄剑莹,林明华,林强,&邹友思.(2005).AIBN/NaNO_2/FeSO_4.7H_2O存在下苯乙烯本体活性自由基聚合.. |
MLA | 颜明发,et al."AIBN/NaNO_2/FeSO_4.7H_2O存在下苯乙烯本体活性自由基聚合".(2005). |
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